I was surprised and pleased to learn that human enhancement technologies not only exist, but are within the reach of the basic electronic hobbyist. This instructable is (of course) for educational purposes only and you may be violating local laws by constructing and/or using the device described here. The author of this instructable is not liable for the burns, permanent neurological damage, or other personal injury up to and including death that may result from building and using the device described here.
Transcranial Direct Current Stimulation (tDCS) is a method of external neural modulation that uses a small current run through the brain in order to alter cortical excitability. The details of the mechanism of action and exact enhancements possible are beyond the scope of this article, but start with the wikipedia entry, examine commercially available products, and look at safety data and ethical reviews before deciding if this is something you would like to pursue. Some google scholar searches will turn up interesting things too.
The photo on this page is from this article.