Step 1Pros and Cons
If you've got old disks you want to get rid of, first think whether there might be someone able to reuse them before drilling holes in them and tacking them to your shed roof! Software, music and films might be of interest to your friends or families and are often accepted by charity shops as a good product to sell on.
For junk mail CDs and badly damaged or scratched CDs/DVDs, it is better to reuse them than throw them away or recycle them. If they can be of use for another 5 years before needing to be replaced then that's better than transporting them to a recycling plant to be melted down and MUCH better than them just taking a trip to landfill. Landfill is a dark, scary place!
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What about the roof peak? How do you solve that? Are there 45 deg bent CD/DVDs? Even on a small scale like a shed, I'd like to see this done. Millions of these things are discarded each year in landflls and on sidewalks. This would be really cool to see as part of a recycled materials house.
With regard to your question about cleaning polycarbonate with H2O2, it's a mild acid, so it's perfectly fine to use on poly containers without fear of BPA release. Alcohol-containing solutions are also safe.
It should also have the opposite effect in colder areas if the CD is flipped and painted black.