Chocolate Extract

 by shesparticular
Featured
Chocolate extract can be added to all sorts of baked goods (like super decadent flourless chocolate cupcakes or a rich chocolate terrine) to add some extra chocolaty oomph. The yummy rich and smooth flavor of chocolate extract goes perfectly alongside vanilla, coffee, and other flavorings, and makes any sweet treat extra delicious (and as an added bonus, it's also awesome in mixed drinks)!

For additional chocolaty goodness, check out these Cookie Spoons and this amazing Chocolate Sourdough Bread!
 
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scree says: Nov 9, 2012. 7:22 AM
A lot of hoopla surrounding the 'necessary' amount of alcohol to extract flavor compounds from the cocoa powder. I'd just like to throw my two cents in about the fact that I love that the water is in the shot glass and the vodka in the not-a-shot glass :)
belsey says: Oct 3, 2012. 12:28 PM
This might be a silly question, but what is the advantage of using this when baking (cake or cookies, for example) rather than just using cocoa powder? I can see the advantage when making drinks (although I've made some pretty tasty cocktails with cocoa powder) but for baking it seems like it would just add more steps for similar results. That said I still think it's cool and I'm going to try it out, but I thought you might have an answer before I launched into a full double blind scientific study...
AussieAnglerGal says: Sep 26, 2012. 3:29 AM
is there a substitute for the alcohol?
shesparticular (author) in reply to AussieAnglerGalSep 26, 2012. 6:04 AM
Unfortunately alcohol is kind of the basis of this and other extracts. It does cook off when the extract is used though.
bgoldberg1 says: Nov 13, 2011. 11:29 AM
I wonder if steam distillation would produce similar results.

It certainly would be faster.

If anyone does try making steam distilled cocoa, please post an instructable! Also, please try a few different liquids (water, vodka, everclear) as solvents, and tell us how the taste changes.
chikid68 says: May 8, 2011. 11:07 AM
I wonder if everclear or some other higher alcohol content liquer would yield a more potent extract .
I know it does when making vanilla extract from vanilla beans so I would assue it does with chocolate as well
starthorn in reply to chikid68Jun 8, 2011. 12:28 PM
Actually, I read an article where they tested this, and they found that 10% more vanillin was extracted at 47.5% ethanol than 95% ethanol. Standard vodka will do better than everclear (for vanilla).

Remember, a lot of the flavor compounds you're extracting are alcohol soluble, but some of them are water soluble. If you don't have enough water, you'll lose out on that flavor.

(Data Source: http://www.reunionfood.co.nz/vanilla-research.htm)
shesparticular (author) in reply to starthornJun 8, 2011. 12:32 PM
Thank you so much for that additional info, starthorn! That makes a lot of sense.
shesparticular (author) in reply to chikid68May 8, 2011. 11:12 AM
Could work - please let me know how it turns out if you try it! I've only ever made vanilla extract with bourbon but higher content booze would likely make the extract more potent.
chikid68 in reply to shesparticularMay 8, 2011. 2:51 PM
i will let you know how it turns out although i ay do 2 batches one with vodka and one with everclear to compare results
shesparticular (author) in reply to chikid68May 8, 2011. 6:19 PM
Sounds great, thanks!
lynnejackson says: May 23, 2011. 3:56 PM
I LOVE This!!!!
shesparticular (author) in reply to lynnejacksonMay 23, 2011. 4:30 PM
Thank you!
FireLite MS2 says: May 9, 2011. 11:23 AM
I used this, but with dried chipotle peppers instead of cocoa powder, and I used gin instead of vodka. it turned out great, actually.

also, using scotch with vanilla is a really good idea, and goes good in chocolate chip cookies.
spark master in reply to FireLite MS2May 12, 2011. 9:38 AM
so then you didn't do this, you made pepper extract
FireLite MS2 in reply to spark masterMay 12, 2011. 10:54 AM
well, yeah, but same concept. it's an extract, therefore, (almost) same product!
shesparticular (author) in reply to FireLite MS2May 9, 2011. 11:35 AM
I love doing vanilla extract in bourbon, but I'm sure whiskey would be great also! Awesome suggestion with peppers - that sounds great!
walshlg says: May 8, 2011. 9:21 PM
please never consume everclear or any other extra high potency alcohol. The concentration process uses toxins, like benzene and ether, these are known to cause cancer. Distillation is the only reasonably safe concentrating process used commercially that I've ever run into. You could extract the water with absorbants but I've not seen that for sale.
spark master in reply to walshlgMay 12, 2011. 9:42 AM
everclear is higly distilled alcohol nothing more, it is not "pure" there is water. and if higher potency booze yields better extracts then as mentioned before simply do not add water to the mixture. nice instructable, just like the vanilla bean extract one, which brought me here
Scurvymcdiggle in reply to walshlgMay 9, 2011. 8:37 AM
as far as i have been able to find out it is just distilled.
tkjtkj in reply to walshlgMay 9, 2011. 8:24 AM
I've no idea what 'everclear' is .. Is it some extra-concentrated alcohol? It's impossible to make 100% alcohol by distillation alone: but there are ways of doing so that do not involve adding anything at all to the highest-distilled alcohol , which i think is about 93% :

Im not recommending this for any purpose except for some laboratory use , but: If one puts a 'wide-mouthed' container (ie, a shallow pan) of alcohol into a closed space in which there is also a pan of H2SO4 (ya, sulphuric acid) , the acid will, over time , draw into it any humidity from the air in the enclosure. So that the partial pressure of water in the water-alcohol mixture is now higher and water will move from the mixture into the air, where the highly 'hydroscopic' acid will continue to absorb it. I recall that its possible to obtain very high concentrations of alcohol in such a fashion. Of course, upon storage, the alcohol will begin to suck up H2O from the atmosphere, so tight sealing is a container with little or no 'dead/empty airspace' above the alcohol is necessary.
Sulphur salts are not going to move into the air within the enclosure. Nonetheless, I suggest untrained/unprepared humans keep their sulphuric acid where it should be: in your car's battery!

I only mention this because its totally irrelevant to the 'structable, which is a fine project and well-explained!
Thanks, Shesparticular !
Scurvymcdiggle in reply to tkjtkjMay 9, 2011. 8:39 AM
everclear is 95% not 100% everclear is not some magic evil liquid. its just rot gut.
firestarter24 in reply to ScurvymcdiggleMay 9, 2011. 11:52 AM
Everclear is 190 proof or 95% ethanol in water (same thing). It is the highest concentration of ethanol you can get using regular distillation methods. Most 200 proof or 100% ethanol are used for chemical research. These do contain ~0.01% benzene, ether, or another additive to break past that 95% concentration barrier, and for this reason, SHOULD NOT BE CONSUMED. There are some other ways to get 100% ethanol without the toxic stuff in it, but those methods are rare, very expensive, and used for chemical research that needs absolute purity. Bottom line is that if you buy it outside of a chem lab, distillation was used to make it, don't use any alcohol over 95%, and don't drink straight 95% ethanol.
shesparticular (author) in reply to tkjtkjMay 9, 2011. 8:30 AM
Thanks so much for the info! Personally, I'll just stick to vodka since it works well and is more readily available in my area than Everclear (which also kind of makes me nervous).
firestarter24 in reply to shesparticularMay 9, 2011. 11:57 AM
Vodka was a good idea (unlike gin) because it is just 35% ethanol and 65% water. On a side note, if you wanted to find out the strength of a drink or any other ethanol diluted mix just use the following formula...
[(% alcohol) x (volume alcohol)] / (volume of final diluted ethanol mix) = (new % ethanol)
shesparticular (author) in reply to firestarter24May 9, 2011. 12:00 PM
Thanks for the formula, that's very helpful! Personally I wouldn't want to drink this (or any other extracts), as they're best used in things (I think).
Pattus says: May 4, 2011. 11:51 PM
Can I ask why there is water and not just the alcohol?
shesparticular (author) in reply to PattusMay 5, 2011. 3:48 AM
Thanks for the question! As far as I know, both are used because if only vodka was, the alcohol content would be too high, causing the resulting extract to cook off too quickly when used and evaporate too quickly.
Pattus in reply to shesparticularMay 5, 2011. 9:41 PM
Thanks, I thought maybe there was something in the cocoa insoluble in alcohol.
shesparticular (author) in reply to PattusMay 6, 2011. 3:59 AM
Well there's that also, but vodka is 80 proof (40 percent alcohol), so there is already some water present.

Awesome question, thanks!
Pattus in reply to shesparticularMay 9, 2011. 4:58 AM
What final volumes are people getting?

I looked to have about 30-40ml (30ml ~= 1oz) after a day or so filtering.

The mass was fairly solid but moist and I couldn't squeeze much out of it without tearing the paper.

It definitely didn't have another 60mls in it though.
shesparticular (author) in reply to PattusMay 9, 2011. 5:03 AM
I ended up with roughly 1 1/2 to 2 ounces.
jsavinc in reply to shesparticularMay 8, 2011. 8:10 AM
I think this doesn't make sense, the chocolate aroma will not evaporate along with the alcohol, because if it did, even adding water would not prevent its evaporation, besides, you still get chocolate flavoured food despite it being cooked on high temperatures.

I'd say it's perfectly okay to use just alcohol in the recipe!
shesparticular (author) in reply to jsavincMay 8, 2011. 8:17 AM
If you want to use just alcohol, that's totally up to you - it's just been my experience that a 2:1 ratio of vodka to water yields a better extract than one that's alcohol alone. If you try different ratios and find that one is particularly effective, please do let me know!
nutsandbolts_64 says: May 8, 2011. 9:03 PM
What's with the vodka?
shesparticular (author) in reply to nutsandbolts_64May 9, 2011. 3:45 AM
Vodka (or other alcohols) are pretty standard for making extracts for baking, etc.
ilpug says: May 8, 2011. 4:01 PM
nice. i got a bunch of those tiny bottles of vodka at christmas, and since i dont drink, ive been trying to find a use for them. this is perfect!
shesparticular (author) in reply to ilpugMay 8, 2011. 6:19 PM
Sounds like a fantastic use for them!
cunningfellow says: May 8, 2011. 3:51 PM
Here's a thought to those wanting stonger alcohol. Instead of adding 2 parts alcohol and 1 part water, use more alcohol and less water. That's the same as using stronger alcohol, don't you think?
imusewhipped says: May 8, 2011. 12:51 PM
I've done a similar thing to make cinnamon essence using Spirytus Polish spirit, which is 96% alcohol (192 proof) I wouldn't recommend drinking it, but it's excellent for making essences that you're going to use drop by drop.
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