Step 6Soldering
Usually people say that joints should come out looking shiny, but this is only true for lead-based solder. Lead-free joints will have a duller surface finish, but still be perfectly fine joints. With either type, the solder should cling to or wet the surfaces, and not just sit on top of them. It should form a smooth ramp and feather out across the pad. The above link also has some galleries of good and bad joints.
It's a good idea to check the part for correct alignment after soldering one pin. Adjustments can easily be made at this point by reheating that one pin, but once multiple pins have been soldering, the part may need to be completely removed to adjust it.
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There are several sites like http://www.wiringharnessnews.com/Articles/1999/SOLDER/solder.HTM that have similar comments about lead-free:
"We will need to re-train our inspectors because the solder joints will look different. They will have a little more white in them; they will not be as bright and shiny, and we will not like what we see. The wet-ability and shape of the termination will look the same but the brilliance will be different."
In my testing, even cheap RadioShack 25W irons get hot enough, although you'll have to wait for a while in between joints for the tip to recover. Here's [http://www.kester.com/en-us/documentation/Alloy%20Temperature%20Chart%20(17Nov04).pdf Kester's alloy temperature chart] that shows a bunch of melting points for a variety of lead-free solders.
Please don't take this to be stubborn or argumentative, I'm just trying to provide references for my claims. It sounds like you've experienced / heard things differently, so I'd be interested in hearing the rationale / experience.