Step 6Pressurize
Hooking the valve to the bike pump I found I had good results at about 20psi. Experimenting here with different pressure may produce different effects. It's important to know that over pressurization will cause your paint bottle to fail, most likely at the nozzle connection. Start with a low psi and gradually work your way up.
Keep an eye on your connection during pressurization to ensure no leaks have spring. I had my bottle up to about 25psi and have yet to notice any leaks. Over-engineering your sealed connections is a good thing here.
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As long as the bottle was originally for soda drinks, it should easily handle 6-8 bar. I did so once for a water bottle rocket contest; the pump was the limiting factor here. We pressurised the bottles repeatedly up to about 7 bars and abused them as they tended to end their flights against concrete and metal walls...
If you want to go that high though, you might want to reconsider both valve-ends. Holes are weak points in pressurized containers.