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Desulfator for 12V Car Batteries, in an Altoids Tin

Desulfator for 12V Car Batteries, in an Altoids Tin
Hello Everybody!

After a year or so of reading and drooling over other people's wonderful projects in these pages I decided to finally make one of my own. Here is my first instructable, a version of the ever popular Battery Desulfator, which I built in an Altoids tin.

First, some background:

My urge to build this project came when my wife's car refused to turn over after a three day weekend away. Here in Tokyo, during winter, the temperature can drop to the low 20's (F) at night and since we have no garage, her car just has to endure the cold as best it can. Many people don't realize that you don't have put up with repeated jump-starts or run to the nearest garage and plunk down 7,500 yen ($85) for a new battery every time this happens. Your old battery may just have built up a layer of lead sulphate crystals on its plates and that is preventing the acid from contacting them over their full surface area. This is caused by subjecting the battery to long periods of insufficient charge, as in the cases of unplugged golf carts over the winter, infrequently used automobiles, and PV systems that don't get enough sunlight to charge their batteries. The result is a great reduction in the battery's ability to produce electricity.

With a desulfator circuit you can reverse this process and rejuvenate the battery to like new condition. You can also save money and prevent water and ground pollution at the same time by keeping your old battery out of the local landfill. As long as nothing is seriously wrong with the battery it can last many times the two or three years that people typically use them. You can even get free batteries from garages that routinely throw them away, desulfate them, and never buy another battery again. Save money and help the environment - now there's a green ecology scheme I can get into!

Most DIY desulfator circuits in use today can trace their roots back to an article in issue # 77 of Home Power magazine written by Alistair Couper in June/July of 2000. Many versions were spawned by his design but they all accomplish the same thing, that is, they use various pulsing circuits to force the lead sulphate crystals back into the electrolyte thus rejuvenating the battery and restoring its lost capacity. The version I chose uses an NE555P timer chip for the multivibrator front end and two coils, a low ESR cap, a fast diode, and an N-channel MOSFET (hereafter referred to as a FET) to generate the high voltage (50V) spikes in the output. Credit goes to Ron Ingraham for changing the design to use an N-channel FET instead of the harder to find and more expensive P-channel types in the earlier versions. Along the way I couldn't resist adding a few tricks of my own to make the design more convenient. See this link for a description of the theory and other information on desulfators.

This circuit can be used three ways - as a standalone device powered by the battery under test; as a standalone device but used in parallel with a battery charger; or built into a charger so that the two work together as one. I chose the third option for my circuit but added a switch so I can use either device independently. Mounting the device onto my charger also allowed me to use the charger's output cables for both functions and avoid the tangle of wires that inevitably results at the battery.

Once properly adjusted, the desulfator can be left on permanently whenever the charger is charging. Just be aware that no matter what configuration you choose, the desulfator is powered by the battery under test so if you use it without a charger care must be taken to avoid deep discharging the battery.

High power versions of these circuits can be built for off-grid solar-cell systems as well where many batteries are typically arranged in series/parallel banks and attached to inverters to produce 120V AC. These battery banks can be desulfated en-masse while being charged by their solar arrays for a truly self-maintaining system minus the periodic checks for electrolyte level, as long as the desulfator circuit is scaled up in size sufficiently.

The Altoids can is the perfect box for this project as the circuit neatly fits inside it and the metal construction can shield much of the RFI that may be emitted by the output stage. You can't beat the price of these tins, and they even come with free mints, or do the mints come with a free tin, I forget... ?

So with the background out of the way, let's get to work!
 
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Step 1Circuit Schematic and Parts List

Circuit Schematic and Parts List
Here is the schematic and parts list, along with some of my pencil notes.

The list is complete except for some parts (two pots, two resistors, two switches, a LED, a FET and some grommets and pop-rivets) that I salvaged out of my junk box. Feel free to do the same, just keep to the values on the schematic as much as possible. Please note that C4, a 100uf 25V electrolytic capacitor, must be a "low ESR" type (Equivalent Series Resistance) to limit its tendancy in this application to get hot. If you choose to use trim pots instead of resistors for R2 and R4, as I did, be careful with the adjustments as C4, D2, L1 and L2 can get very hot if the 555 chip is made to send too wide a pulse into the output stage. The resistor values in the schematic should program the 555 chip to output pulses of the proper width and limit any excess heat buildup, however. We'll discuss this further in the Smoke Test Steps.

The LED can be any standard type and will only turn on when pulses are present in the output. S1 should have at least a 3A rating, and if you use a DPDT type use both sets of contacts in parallel to reduce the contact resistance as much as possible. S2, at the output of the 555, isolates the 555 from the output stage allowing you to make adjustments to the front end without risking overheating Q1, D2, C4 or the inductors.

The inductors I chose are listed on the schematic at the bottom of the "Possible Inductors from Digikey" list. They fit the can nicely but will need to have one lead extended slightly to reach the bottom of the circuit board. In retrospect, an inductor with a slightly higher current rating for L2 might be better as the one I chose gets noticably hotter than L1 even though it has the same current rating of 2.4A. Digikey part number M8875-ND should fit the can, barely, and has a 3.6A rating, but the 2.4A coil that I'm using now really only gets hot if I get too aggressive with the pulse width adjustments.

D2 is a FRED (Fast Reacting Epitaxial Diode) and should not be substituted with any old diode in your junk box as the latter will probably not work well in this circuit. If it gets too hot you can use two in parallel to double the current capacity, but again, if you keep the pulse width on the conservative side it will only get slightly warm.

The FET listed works very well and is inexpensive. I mounted mine directly on the perf-board with a piece of stick-on copper foil (available from Digikey) under it to act as a heatsink. In this configuration it doesn't get warm at all so the copper foil may not actually be needed. Be aware that the metal tab on the FET is also attached to pin 2 (drain) so if you attach the FET to a heatsink you'll have to electrically isolate it from the rest of the circuit. I also used a TO-220 transistor socket to allow easy replacements but you can wire the FET in directly if you prefer. Just avoid touching pin 1 (gate) while handling it as it is very ESD (static) sensitive.

Also, I opted to use the "Turn-off Enhancement Circuit", shown in the schematic as Q2, D3, and R5, as it helps the FET to turn off more precisely. If you use these parts do not use C2 and R3.
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Apr 29, 2012. 1:57 PMdidyman says:
Another working one! Thank You for the instructable! It's a prototype, so design will surely change later. Especially for the location of C4. At first, i have forgotten to connect the enhancement circuits' PNP Base to the rest of the circuit, so there was no fast turn off and everything got warm too quick-finally the IRF2807 has gone.. So replaced with IRFZ44N and noticing the missing joint and....Works everything well. C4 and C1 also is a Yageo SC. It's low-ESR type, not the best available here, but i have some in spare. Gets so hot, but not that much. Some interesting notice. 555 output is fine, and so the output pulse. Everything is fine, and not very warm to the touch with a single 54Ah car battery, but after i tried it in my vehicle, with a 75Ah one. And there, it runs much hotter. And from the sounds intensity, it just turns lover at once and then climbing up louder slowly, then again, turns down. This also affects heat dissipation. What is interesting, the peak voltage reading is around 43V in both case (a 1N4148-100nF single peak detector is placed at the cables very end near to the battery).
The car is a Peugeot 205, no ECU in it, and the Pioneer radio seems unaffected, no 1kHz signal from the speakers in any mode, exept AM receiving, certainly :-)) . Now it's cyclic desulfating, as i don't like to leave alone this proto. Results-i will come back and tell!
Ahm, LED. I got a white one, and that works only in reversed. It shows that the FET opens, and i think its enough to state that pulses are generating. But i will try red ones later.
Apr 30, 2012. 5:03 AMdidyman says:
I have a client wich is an auto repair dept. I usually meet with this "don't think just throw it" mentality, but i always try to refuse. Original parts are horriblic in price, and the electronics aren't examples. And if it can be disassembled, there are good chances to repair (heh, cables, cheapo parts, relays, capacitors-everything that can go wrong in any regular product..). It's not only a value for-effort, but an environmental, too. And these batteries are take a much bigger toll than that the dealer asks for them at the shop. It's simply unbelievable, why there is no bigger efforts to save batteries with such a simple solution for a problem, that may be the main reason behind battery aging. I have measured 26V on the battery's terminals, 60V on the electronics (the measured 43V was on the fuse holder near the crocos) with the simple peak detector and the most voltage seems still loosing on the crocodiles, or on the wires attached to the battery-so further measures will take place, and maybe the mentioned ferrite ring will help more. Some not so important changes: I have BC556 at home for PNP, and BYW29F-150 for the FRED (as watching its forward characteristics, with 60A peak, developing only 1,2V on it, i can't believe it's enough for a red LED anyway with the currents the circuit is able to produce, but i will try it anyway-the FR602 has a noticably higher rdiff, so it easily can light up a lower Vf LED). Later, i will try to optimize circuit paths (but this probe-panel has two straight lanes in its middle, so i built up the higher current paths accordingly, and the FET's gate drive crosses it, but for this reason i placed the enhancement circ near the FET and let that crossing line see the low output impedance of the NE555. And it seems, as the peak is so narrow, the cabling has to be not only short, but free from narrow turns and parasite capacities. I think, these little thoughts may be useful, because we want to make sure the more energy reach the battery and not loosing on the path to it-again, some measurements will prove if they are valuable. And again, Your instructable is very kind, very practical and interesting, anybody could learn from it! And, some pics-may or may not interesting, but i show them :-) . It's a proto, so it looks like that (yes, i know: Things are made for temporary solutions tend to last for longer than anything else :-) ).
Apr 18, 2012. 7:33 AM2009ee195 says:
Hi KMPRES

I've made and assembled the circuit, made my own inductors as they were unavailable in the market. I can hear humming sound from the inductors, but have to place my ears very close. the led is also glowing but when i checked voltages and ampere with multimeter the dc voltage was 15v as i think because of zener diode and the current is just 0.1 amp this is not good can you tell me where i m going wrong?
Apr 13, 2012. 11:46 AM2009ee195 says:
Hi Kmpres How r u?

Kmpres i was giving a look to charger section of your instructable, i was unable to to understand.

Did u attach the circuit parallel to charger and then attach it with battery?

If you attached parallely doesn't it affect the charger?

Or If u really attached parallely with charger can i use power diode to stop pulse going into charger, kind of insulating charger from the circuit output but on the same time using charger current as source?
Mar 31, 2012. 12:04 PM2009ee195 says:
Hmmmm. So i think i have to stick in this design and wait for recovery for long.....well any idea how much time it will take to refresh my 200 amps battery well theoretical results are far from the practical ones
Mar 30, 2012. 2:13 PM2009ee195 says:
Hi Kmpres
Bro, i want to test this circuit on a 12v 200a wet cell battery, what i want is to give it life again in a week, what certain changes do i needed to do in your circuit? can u help me out.

As i read your previous comments i think that this circuit can work on one ampere hour ratting. if i am right the circuit will take 200 hour to fully refresh the battery.

here i have a power break down issue and i want to use it as soon as it get refreshed minimum i can wait is one week. so please help me out.
Nov 19, 2011. 8:02 AMjbaker22 says:
I don't won't to devalue your instructible, but it seems like you payed double the price of a desulfater in your electric bill. There are desulfaters that run off a 12 volt float charger (550MAH).
Nov 26, 2011. 9:19 AMjbaker22 says:
So, how long did your desulfated battery last anyway?
Jul 2, 2011. 6:20 PMStefanovski says:
Hi i was looking for desulfator who can desufate much quicker. I found that batterydoctors.com (my neighbor is on of them) have some technology that allow they to desulfate car batery for one day. I found that 3,26 MHz is optimum (magnetic resonance) and find this interesting schematic
http://1.bp.blogspot.com/_X7IYGjOz8_0/SljTnoVMhPI/AAAAAAAAAII/8W4Q7qxwhfY/s1600-h/hi-low+charger.JPG
Because I rockie in eletronic, can you and other see and coment. This is the blog http://poormanguides.blogspot.com/2009/05/updated-chargerdesulfator.html
Sep 18, 2011. 3:30 PMStefanovski says:
I bild this http://1.bp.blogspot.com/_X7IYGjOz8_0/SljTnoVMhPI/AAAAAAAAAII/8W4Q7qxwhfY/s1600-h/hi-low+charger.JPG and using it like a charger for you're desulfator it gives around 1,6A 120Hz will it be ok to work in paralel with youre desulfator I conected there was no problem but I dont know for how long any sugestion ?
Jul 3, 2011. 4:46 PMStefanovski says:
thanks for the advice
Sep 6, 2011. 4:31 PMa_hakeem says:
Dear Mr. KMPRES, You are the MOST kind person with big heart i ever met through web sites.

I am very glad to be a member among all cleaver and high educated members.


With regards to all

I am : asad al hakeem from IRAQ
Aug 30, 2011. 9:50 AMfortunare says:
Does anyone have a spare version of this desulfating charger that works which you'd like to sell? Haven't got the time or patience to build one myself but would like to try one. thanks, Mike. fortunare@cox.net
Aug 5, 2011. 7:25 AMmanoj.patil.1974 says:
Hello, I looked on the internet to find the 555 astable multivibrator formulae. All the circuits out there have C3 tied to ground, however you have tied it to Vcc.

Also, if I insert 15K, 270K and 0.0047ufd in all those calculators available on the internet, it shows a 50% duty cycle with 500Hz.

Can you pls help here. I seem to be doing some wrong ?
Aug 5, 2011. 11:25 AMmanoj.patil.1974 says:
I do not have a scope so a bit struggling with that. With the 15K, 270K values, what is the duty cycle ? and what changes of R2 will vary the duty cycle by what value ? that will help me to put the right R2 there so that i know the duty cycle is in control and not blow up my power section. Is there a formulae or something ?
Aug 5, 2011. 6:54 PMmanoj.patil.1974 says:
Alright. Looks like I have to get hold of a scope to find out the new value of R2 that would double up the current duty cycle of 8% ( right?). Would you be atleast able to tell me if the duty cycle would double up if I double the value of R2 or some sort of such guidance based on your experience with the pots ?

My circuit is working. I hear the very faint humming noise. My Q1 is almost cold, L2 is 6A rated so almost cold. L1 is almost hot. C4 ( i have used 5 22ufd in parallel, so they are luke warm), the 2 FR306 are slightly warm.
My L1 is rated at 2.2A. Any views on why only that component gets hot ? May be its because its rated at 2.2A and the current flowing through it is higher or close to its rating. Is it a must that L1 should be 1000uh ? can i replace it with a 220uh as I have more of them and they are rated at 6A.
What is the effect if I use a 180ufd capacitor instead of 100ufd ?

I have a 200AH 5years old inverter battery. After leaving the inverter connected for 8 hrs and then disconnecting, the no load voltage of the battery is 13.5V. However, as soon as I connect the inverter and start my fans and tublights in the house, within 5 min, the voltage drops to about 10V and the inverter trips due to low battery voltage.
If I leave the inverter connected for 8 hrs to charge the battery fully and then disconnect the inverter and then connnect the desulfator, the voltage starts at 12.4V, the components get heated, faint 1Khz noise heard etc and then after 8 hrs, the voltage drops to about 11.3V and the heat in the components is also reduced which indicates that the desulfator is not able to take up enough current from the battery as its discharged....

From the above description, do you think this battery is a good candidate for resurrection using this desulfator ? I have left it connected for last 2 days and I am not noticing any significant regneration of power in the battery... may be I should leave it connected for several weeks.

I am also thinking to use a R-C voltage doubler kind of a circuit across the battery to check the max ripple voltage using a voltmeter. This will also help to ascertain if the circuit is really ringing and providing the pulses. I guess this may be a slightly accurate way instead of the touching components for heat or the LED (which in my case does not glow, may be because I have connect two FR306 in parallel)
Aug 23, 2011. 10:49 AMmanoj.patil.1974 says:
Hi,
Thanks for your responses. Unfortunately with no scope handy and no budget to a new one, I have to keep experimenting.

I have used a simple diode and capacitor as a peak voltage measurement tool. When I connect a 10 ohms, 50W resistor as load to the circuit and power it through a 12V, 10A SMPS supply and connect the peak voltage circuit, I see about 45V at the D2 and about 37V at the resistor load.

However, when I connect this to the battery and do similar measurements, I get around 20V. So not sure, why the voltage drops so much at the battery.

May be there is a lot happening out there....

Aug 24, 2011. 11:33 AMmanoj.patil.1974 says:
Hi Kmpres

Some more observations as I continue to work on this

Lets say A and B are points of + and - on the ckt board and C and D are points of + and - at the tips of the cables

Now to test the circuit, instead of using a battery, I used a PC power supply SMPS to provide 12V.

When no load is connected, the readings are
A to B 48V
A to D 42.5V
C to D 40.8V

When I connect a 10Ohms, 50W resistor across C &D, I get following
A to B 45.9V
A to D 39.8V
C to D 38V

Now, to further experiment, I connected a Power Diode to the positive cable of the SMPS ( so that the pulses don't enter the SMPS) and here are the readings

No load
A to B 61.9V
A to D 61.4v
C to D 62V

When I connect the 10 ohms, 50W resistor, the readings
A to B 49.2
A to D 48.2
C to D 48.3

Also, I noted that when I connect the SMPS through a diode, and without any load to the circuit, the transistor quickly start heating and gets hot. This indicates that all the energy in the inductors is finding its way only through the transistor.

However, when I connect this to the battery, the readings at battery is around 20V.

So my conclusions.
1. The voltage drop is majorly due to the sulphation in the battery and not due to the leads or the peak detection circuit. Now should the voltage drop from like 48v to 20v is a question I have no answer to. In your case, you get 36V. But I guess yours was a simple small Car battery which are I guess 40AH capacity. Mine is a huge inverter battery of 160AH capacity and is a 6 years old regularly used battery and has stopped providing much of capacity so indicating that there is a lot of sulphation.... so may be the voltage at the battery terminals is an indication of how much the sulphation is... :)

2. My idea of the peak detection really worked. Its a simple circuit of a diode and a capacitor connected across the measurement points. You commented that it may be loading the circuit, but since there is a diode, I think once the capacitor is charged to the peak point, it would stop drawing any current and thus not really overload. This is a very easy fix to the costlier option of buying an oscilloscope.

3. I have also changed the wiring of the 555. I used the circuit and calculations available at
http://www.horrorseek.com/home/halloween/wolfstone/TechBase/com555_555TimerCalc.html
I used R1 = 29.3K R2 = 322K and C = 0.0041ufd
This as per calculations gives me 8.34% duty cycle and 1000Hz freq. Now since i did not have a scope, I chose to this config so that I atleast have some calculated proof of the frequency. The inductors are humming and that is another indication that the circuit is really working at 1Khz.

Enough !!! I guess I am going to stop any more experiments and leave the circuit connected to the battery..... for weeks and weeks and hoping that some day, the sulphation cracks up and I get a better performing battery....

Feb 13, 2009. 5:47 PMsmetana says:
Hey , cool project. I saw it a few days ago and really wanted to make one. Tonight I finally heard the wine a the led lit up. I wound my own coils around some toroids I had. I'm sure the inductance is way different than what is in the schematic, but it at least makes some noise. I found a FRED in an old computer power supply, and the rest I had laying around. I'm not an electronics guru, and I was wondering if you really understand the path of the current through the FET and the two coils and the FRED and capacitor. What is really goin on. I've tried to figure it out, but my I'm not getting it.
Aug 5, 2011. 7:42 AMmanoj.patil.1974 says:
Hi, can you pls check if you have used L1 and L2 alright in this response.

Looking at the circuit, when Q1 is not conducting, capacitor C4 will charge through coil L1. And when Q1 is conducting, C4 will discharge through L2.

Pls let me know if I am wrong.
Feb 15, 2009. 5:10 PMogion says:
Ingenious. Simply put.
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