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Electrolysis

Electrolysis
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Electrolysis is the decomposition of hydrogen and oxygen in water. In other words you break apart the molecules that make up water to restore the elements to their original state. In this case both hydrogen and oxygen exist in a gaseous state. In order to perform electrolysis you must run an electric current through water that contains an electrolyte. The electrolyte allows current to pass through the water because pure water, or even tap water for that matter, is not conductive enough to allow electricity to pass through it. The electrolyte I added in this experiment was salt, a common household item.
 
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Step 1Getting the stuff

Getting the stuff
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The materials you will need for this experiment are:

baking soda (it used to be salt but then I was informed that I may have been producing chlorine gas)

Hot water (enough to fill your container of choice)

a container preferably air-tight and definitely clear

a pair of screws (these will act as the electrodes you pass the
current through)

a battery (a nine volt will do nicely for your first try)

Space to work (I barely had any and that made it a lot tougher)

Materials you may want to have, but are not necessary:

a glue gun (to patch up any holes left by the electrodes)

a DC power source so you don't have to worry about the batteries
running out.

a container that can dispense the hydrogen and oxygen (see introduction)

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195 comments
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May 18, 2011. 4:13 AMubuntuPenguin says:
is vinegar a good electrolyte to use? does it produce any dangerous gases?
Sep 16, 2009. 1:11 PMbuckminsterfullerene says:
you shouldn't use screws, the metat that they are made of will probably short out the circuit and will oxidize. you should use carbon rods, you can see this in one of my upcoming instructables
Dec 4, 2010. 12:48 AMtinstructable says:
Platinum is the metal that you should use. Platinum's corrosive process takes much much longer than graphite, steel, etc. The industrial electrolysis machines use platinum for its non-corrosive properties.
May 21, 2010. 4:24 AMTombini says:

You seem to love your carbon allotropes Mr Fullerene :P

Mar 10, 2009. 4:40 PMEl Mano says:
Won't the screws corrode? I've made two good electolysis units that I had to scrap because my electrodes (pencil graphite and steel) corroded.
May 26, 2010. 10:05 PMdragoonpreston says:
The screws will corrode, but the point of this guide is to make a simple Electrolysis unit.

If you want something of a more permanent nature i would recommend getting Stainless Steel Tubing, it will cost more but it wont corrode.
Oct 14, 2010. 10:17 AMAlpha2904 says:
Stainless Steel will rust IF it can not dry. It will take longer but it will still corrode
Sep 28, 2010. 5:09 PMHightechk says:
ty i was wondering what i was going to use
Feb 9, 2010. 2:45 AMI Love Guns says:
I'd rather use salt. Baking soda makes carbon monoxide instead. Not a good idea. The best electrolyte would be a weak acid or base (caustic soda or hydrochloric is good)
Apr 7, 2008. 5:59 PMS3anyBoy says:
I have a charger from my old laptop that outputs DC, but I don't know what would be negative and what'd be positive.
Jan 24, 2010. 4:39 PMjamesmcelroy92 says:
the negative one is usually black and the red is usually red, but if not just using water with salt put both the endsof the wire into the water and the one that has little bubbles coming of it will be the negative..lol.. but dont use pencils( only if you want oxygen aswell)  just use the copper wires but dnt leave them in for to long becasue they will corrode..
Jan 24, 2010. 4:39 PMjamesmcelroy92 says:
*the red is usually positive sorry lol
Oct 3, 2008. 7:17 AMTombini says:
a simple solution (get it) is to set up the apparatus and check which one bubbles ~20 times more. This is the hydrogen
Nov 14, 2008. 11:12 PMprofessorred says:
fyi, there is 2 times as much hydrogen as there is oxygen. not 20.
Nov 15, 2008. 11:15 PMTombini says:
Urrrghh, I meant by volume! Hydrogen is roughly 10 times less dense than oxygen, so if there is twice as much hydrogen you get 20 times in volume. I have done this test many times the hydrogen filled up a test tube and the oxygen was barely 1cm full
May 13, 2010. 10:04 PMelectricmic says:
It is terrific that you are speaking from your actual experimental results. Right on! The molecular weights shouldn't matter- the volumes should be 2 parts Hydrogen to 1 part oxygen. That's why I love electrolysis- it is so intuitively clear (except when it doesn't work as expected). I think your large volumes of missing oxygen must have attached themselves to atoms from one of the electrodes.
May 13, 2010. 8:41 PMelectricmic says:
The mass and size of individual gas molecules has no relation to the volume they occupy when flying around as a gas. Gasses are mostly empty space.  It's fascinating! check out the ideal gas law.

(Actually, all matter turns out to be mostly empty space if you could look closely- check out this link to Rutherford's experiment which measured the nucleus of gold atoms http://en.wikipedia.org/wiki/Geiger%E2%80%93Marsden_experiment)
May 21, 2010. 4:22 AMTombini says:
You're right when it comes to volumetric analysis but I think there is a bit more to a gas than Avagadro's law or an "ideal" gas.  In reality all gasses have intermolecular forces which allow them to liquify and solidify, if there where no forces between these particles why would they condense?
This is where the definition of an "Ideal" gas comes in which is most closely related to Helium (If I remember correctly) because the only intermolecular forces are dispersion forces relating to the instantaneous positioning of electons in an electron cloud.

In gasses such as H2 and O2 (because of there lack of dipole moment) dispersion forces are also present but to a larger degree because of the larger size of the electron cloud and the number of electrons (shown by a higher melting point)

The other intermolecular forces of gasses include dipole-dipole and hydrogen bonding (I think).  Anyway both hydrogen and oxygen have low melting points proving the forces between them are negligable when looking at gasses at around 300 kelvins.
Mar 12, 2009. 3:45 PMDefault117 says:
To correct you on your math: if you were going by densities, then there would be two Hydrogen atoms and One Oxygen atom (if you were to split a single water molocule). The two Hydrogen atoms would equal one fifth of the Oxygen atom.
Mar 14, 2009. 11:15 PMTombini says:
Lol, smartypants... still the basic rule applies, whichever bubbles more is the Hydrogen
Feb 9, 2010. 1:47 AMmarmique123 says:
aww... my friends said that its just boiling water... not hydrogen gas >o<
Dec 4, 2010. 12:50 AMtinstructable says:
Your friend doesn't know what they're talking about. It's hydrogen.
Mar 15, 2009. 10:25 PMDefault117 says:
Yeah... I mean no... I mean... Aww crap Your making me think XD
Mar 18, 2009. 7:36 PMReCreate says:
{{{ }}}
brain explodes
Aug 13, 2009. 6:16 AMbylerfamily says:
brain explodes.
Aug 13, 2009. 4:19 PMReCreate says:
Much better
Aug 14, 2009. 10:04 AMbylerfamily says:
Yeah.
Aug 14, 2009. 11:23 AMReCreate says:
:D Wow look [http://www-jpc.physics.ox.ac.uk/home_status.html JPC] can now boot Graphical linux distros!
Aug 15, 2009. 4:16 PMReCreate says:
I forgot that code does not get executed in monospaced text XD
May 1, 2009. 7:27 PMnodrog19 says:
Equal amounts (by the mole) of gas at the same conditions have equal volume. You will get 2 volumes of H2 and one volume of O2. Look up the ideal gas law.
Jun 21, 2009. 2:00 PMwiebevandomburg.hotmail.com says:
yep , 22,4 liters of gas / mole
Jun 27, 2009. 10:54 PMprofessorred says:
Moles are furry and cute.
Jul 7, 2009. 9:06 PMdigital01 says:
No they are curry and fute
Aug 13, 2009. 10:38 AMprofessorred says:
MMmmm. Mole curry.
May 1, 2009. 7:38 PMReCreate says:
Everything now explodes,including brains
Feb 9, 2010. 1:50 AMmarmique123 says:

hahahahhahahahaha!!

Jul 24, 2008. 2:39 AMbeavercleaver says:
One output wire will have a white stripe or dashes on it, that is your positive. You seriously need a DVOM, they are really cheap, and necessary for any electrical experiments.
Dec 4, 2010. 12:52 AMtinstructable says:
Actually, a white striped wire usually indicates a negative, and dashed indicates positive. It took me a long time to figure that out when I couldn't figure out why all my projects wouldn't work.
Dec 5, 2010. 8:11 PMbeavercleaver says:
Not in the automotive electronics world, dashes do not exist on wires. A DVOM is the only way to be sure what you are working with.
Apr 26, 2008. 8:47 AMezduzit47 says:
Connect a DV volt meter to the ends. check the direction of needle or the polarity
1-40 of 195next »

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