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How to Perform the Genie In A Bottle Demonstration

video How to Perform the Genie In A Bottle Demonstration
This Demonstration shows the catalytic decomposition of hydrogen peroxide.

100mL of 30% hydrogen peroxide is pour into a flask that is wrapped in aluminum foil. A small packet of 2 grams of manganesse dioxide MnO2 is wedged between the rubber stopper and the rim of the glass. When opened the packet releases and the reaction starts.

*****Important Note- There must be hole in the rubber stopper (use a 1 hole or two holed rubber stopper) incase the MnO2 reacts prematurely with the H2O2. It is not a sealed container and will not explode.
19 comments
Dec 4, 2008. 2:38 PMMasterdude says:
Where can I find manganese dioxide or other catalytic substances for hydrogen peroxide?
Dec 8, 2008. 11:48 AMwiebevandomburg.hotmail.com says:
the black powder in batteries (aa or aaa)
Dec 8, 2008. 2:38 PMMasterdude says:
Really? Awesome! That I can get a hold of. Thanks.
Jan 27, 2008. 7:28 AMKeith-Kid says:
You could make sooo many movie effects with this. Very cool Is this toxic in any way? I mean can the fumes make you dizzy or something?
Dec 8, 2008. 11:48 AMwiebevandomburg.hotmail.com says:
the fumes are oxygen
Aug 19, 2008. 6:28 AM5iN says:
regardless of what the answer is, do this in a well ventilated area. As previous posters pointed out, it's steam. steam usually means it's very hot. Not something you want to put your face near
Jul 25, 2008. 5:33 PMaklyatne says:
The aluminum foil is to prevent the breakdown of the hydrogen peroxide into "heavy water"; that's why bottles of peroxide are always dark plastic. Light breaks it down.
Jul 1, 2008. 12:31 PMzstarski says:
You can also use beef liver as a catalyst for H2O2. I don't know what catalyst is in beef liver.
Jul 24, 2008. 6:54 PMKuroiJin says:
The Oxygen in the liver is the catalyst
Jan 25, 2008. 8:54 AMironsmiter says:
INSTRUCTables..... this one would actually be fun to know how to do! why wrap the bottle in foil? what concentration of Peroxide? what else is in there? why is it PINK? Write it up, and tell us HOW to do it ourselves!
Feb 12, 2008. 4:52 PMCytokine says:
I'm about 99% certain that the foil is just for show; it's supposed to be presented as a magic trick; you don't want the audience to see that when you open the stopper the bag of MnO2 drops into the fluid at the bottom.

There isn't anything else in the bottle, just the peroxide solution and the packet of MnO2 after the stopper is removed.

The smoke isn't pink; it's actually steam, the chemistry involved is this:
MnO2 + H2O2 ----> O2 + H2O + Mn+2 (sp)
The reaction is highly exothermic, thusly boiling the water and releasing steam. I think the lighting in the room, or the camera makes it look pink.

I have waaay too much time on my hands :)
Apr 27, 2008. 11:29 AMduct tape says:
Don't you mean:
2 H2O2 ---MnO2---> 2 H2O + O2
instead of:
MnO2 + H2O2 ----> O2 + H2O + Mn2
Because MnO2 is just a catalyst, it does not react with the H2O2 to make manganese metal.
Jun 10, 2008. 5:39 PMCytokine says:
Whoops, you're right- glad I didn't make that mistake on my Chem final!
Jun 28, 2008. 8:43 AMszechuan53 says:
you know you can subscript
2H2O2---MnO2--->2H2O+O2
Jul 1, 2008. 11:34 AMduct tape says:
wait, is it 2H2O2
Jul 1, 2008. 11:33 AMduct tape says:
how? using [sub]x[/sub] tags?
Jan 26, 2008. 12:05 PMaustin says:
it says 30% peroxide, an instructable doesn't have to tell you how it works just how to make it work, if you want to learn the complete reaction and chemistry behind it then look it up. peroxide and manganese dioxide are all that in it.
Jan 25, 2008. 5:53 PMGorillazMiko says:
Yeah... this should show how to do it. It's still cool though, I would like to see how.
Feb 17, 2008. 12:32 PMmdj817 says:
I believe that the aluminum foil is for heat absorption, so the glass beaker doesn't crack from thermal shock. As cytokine said, the reaction is exothermic, and unless that beaker is Pyrex, it would shatter. This is a guess, and, after all, I'm only 12!

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Author:kentchemistry.com