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This is an instructable for how to make gunpowder from its basic chemcials. The cost is initially expensive for the scale and ballmill (a little over 100$) but once you have those parts all you need is the chemcials which are relatively cheap.
 
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Step 1: Parts list

There are three basic chemicals in gunpowder Potassium Nitrate, Charcoal powder, and Sulfur powder. Gunpowder would be a lot simpler to make if you could just mix the three chemicals together in the right ratio and have the final product, however chemistry dosent always work that way. If you look at a piece of charcoal under a microscope you can see very tiny holes called pores. Even when the charcoal is ground up into a fine powder each particle of it still contains microscopic pores. To properly make gunpowder the particles of charcoal must be ground together with the potassium nitrate and sulfur, the process of grinding them smashes the potassium nitrate and sulfur into the pores of the charcoal creating a subastance that will readily burn when ignited.

Parts list:

1. Ball mill ( Can be bought at unitednuclear.com for 70$, if you buy it someplace else or decide to make it, make sure you also buy lead grinding media (ceramic media can also be used) as it is the only metal that wont give off sparks when ground together)
2. Scale ( I prefer the electronic ones which can be bought on e-bay fairly cheap, less then 20$, make sure it has a capacity of at least 200 grams, otherwise you will be making gunpowder in very small batches)
3. Potassium nitrate, Sulfur powder, and Charcoal powder(All obtainable on e-bay) When buying try to buy as close to 5x as much potassium nitrate as charcoal powder, and 2/3 as much sulfur as charcoal ( I will explain the ratios later)
4. Wire spaghetti strainer
5. Old newspapers
6. Tupperware container
7. Calcuator ( To measure the amount of chemical to use)
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spawnos3717 says: Dec 30, 2011. 10:13 AM
could one put a static pad on or in the mill to absorb static and discharge it safely away from aparatus?
stoobers in reply to spawnos3717Jan 26, 2013. 8:23 PM
It isn't a "static" issue so much as if you use steel balls to grind the powder, a steel back will strike another steel ball and make a small spark. BOOM!
ancaf33 says: Feb 5, 2012. 10:22 AM
How do i get the gunpowder to grains?
stoobers in reply to ancaf33Jan 26, 2013. 8:22 PM
For black powder, grains is volume. So 50 grains of lead or 50 grains of powder have the same volume, but different masses.

You can't measure "volumetric grains" on a massing scale. You use a miniature graduated cylinder, calibrated in grains.

However, there is a "weight grain" also.

1 volumetric grain of water is 1 weight grain of water.

I found a 50AE shell casing, and it held very close to 50 grains of water by volume or by weight. So it also holds 50 grains of black powder by volume (but not by weight.)

Black powder by different manufactures and particle size has different weights for the same (or nearly same) substance.

You can buy a black powder measuring scoop (mini graduated cylinder) at a decent gun shop, or order one on-line.
Algag says: Jan 1, 2013. 9:37 AM
I feel like every science teacher I have ever had cringed as you wrote scale and grams. :b
TaylorLA says: Dec 2, 2011. 6:20 PM
How can i make an altanate fire cracker?
Demascus says: Nov 11, 2011. 5:29 AM
have made gun powder years ago, on technique I used was wetting all the ingredients as you mix them. Yes it looks like black mud. However the potassium nitrate will dissolve in the water. Gives everything else a great coating in that form. Will allow for more aggressive forms of grinding to put them all together. Once you have it right. You can use window screen to spread the mud out on and some form of roller or dowel rod (I used a rolling pin) Let it dry and then flex the screen and the little pieces fall out. It worked for me. Other thought is you could use your coffee bean grinder on your charcoal to powder it first. In other words you powder each component separately then mix.
buildingteen says: Oct 28, 2006. 12:56 AM
does it have to be weight or can you just mix 75 quarter teaspoons to 15 quarter teaspoons to 10 quarter teaspoons, and where can you get sulfur?
dvarner in reply to buildingteenJul 29, 2011. 3:06 AM
i buy potassium nitrate and sulfer all the time, i make my own powder, but my potassium nitrate i mainly use on military grade smoke bombs, one smoke bomb the size of a pop can will cover a 2 block area if u know wat ure doin, u can by both at almost any hardware store, plant shop anything like that, i buy a big bottle of dry stump killer for $4 and it last quite a while
MajorBromley in reply to buildingteenSep 8, 2010. 5:15 AM
its not as acurat and u can get it from ebay
dutch712 in reply to buildingteenJul 2, 2010. 6:36 PM
garden store or nursery
liam552 in reply to buildingteenAug 21, 2008. 4:33 PM
the plant shop has sulfur for fertilizer.
Tetranitrate (author) in reply to buildingteenOct 28, 2006. 1:23 PM
It has to be weight, its the only sure way of measuring the proper amounts.
JamesRPatrick in reply to TetranitrateAug 23, 2008. 4:41 PM
Yeah, if you measure by volume, it'll probably screw you over. Particle size and thus space between particles varies from different suppliers.
JamesRPatrick in reply to JamesRPatrickAug 23, 2008. 4:43 PM
In a different experiment, measuring by mass made a smoke bomb; measuring by volume made a rocket.
benthekahn in reply to TetranitrateJul 29, 2008. 11:46 PM
Not to be technical, but its actually in mass.
fennecfanatic in reply to benthekahnApr 15, 2009. 7:00 PM
Pathological circumstances notwithstanding, units of weight and units of mass are generally interchangeable on Earth at reasonable altitudes.

Even more technically speaking, electric scales measure weight, not mass. Consider an object resting on a scale falling in an elevator. The mass of the object does not change, but the readout on the scale would, due to the lower effective gravity.

The only accurate way to measure *mass* is to use a balance, since both ends of the scale would be affected equally by whatever gravity there is, and so the reading would be the same.

Mmm... physics. =)
dutch712 in reply to fennecfanaticJul 2, 2010. 6:45 PM
if your mind wondering this much, don't play with this stuff, you could smart yourself right in to the burn unit of the nearest hospital. You have had pain till you have had a powder burn, it fells like it goes inside the pores and burns it s way out.
cseaman says: Jul 2, 2011. 10:33 AM
also united nuclear has chemicals so you can get just about anyhting you need from there.
milamber says: Dec 21, 2009. 8:12 PM
 ok so kno3( potasium nitrate ) is a 5.1 oxidiser yes?>
chlorine is a 5.1 oxidizer so could you substitute kn03 for chlorine?
pastaking in reply to milamberMay 31, 2011. 11:14 AM
No. Chlorine would prevent the reaction from taking place. If you are talking about Pool Chlorine tablets, that's another matter. I think you can use them, but you will have to look it up.
beehard44 in reply to milamberDec 11, 2010. 5:50 AM
chlorine is a gas
MajorBromley in reply to milamberSep 8, 2010. 5:20 AM
i dont think cloren can ige nit maby im wrong try it
xfox44mag says: Feb 4, 2011. 11:19 PM
the olny thing i gring is potasium nitrate and chracoal for griding your stuff you can use a coffe grinder it works grate just never grind it all at the same time and clean it every time you swich to grind outher stuff
ok now win you mix it do not use water that kills black powder or gun powder in the old days thay use alcohol 100% or 90% i use everclear lol you do not need to use a lot just a nuff to get it damp the reson for this is so you do not blow your hand off it keeps the powder fom exploding till it drys out makes it a bit stronger too but not a lot i ues this mix in my guns and i need 0.7cc more then the storng nonsmoking stuff you can buy in the gun shop the mix i ues is 75% potasium nitrate 10% sulffer 15% charcoal use a soff wood chracoal and the more you put in the faster it will brun i made a fast mix with this form 70% potasium nitrate 10% sulfer 20%charcoal if you look for some were to buy stuff you can get it a lows stump remover is potasium nitrate just shaks the can to make sher its dry stump remover on the same rack look for sulfer dust for killing mights o and on the buttom of the can a big cap lol now you can make the chracoal just burn some soff wood i use balsa i build r/c planes so i have a lot of scrap it works beter then pine makes it burn to slow
o and BQ charcoal not the same thing and you do not need a ball mill i have made it bouth ways and the mess of the ball mill not worth it i just mix it in a coffe can with a stick i ues this in my cannon too works grat and buy fuse form a fire works sulpier its a lot cheper you can get 50ft for under 20 bucks i got 150ft for 35 on sell just shop around thers a lot out ther you just got to look and if your in can you can still get the stuff you just got to know what to look for
pastaking in reply to xfox44magMay 31, 2011. 11:12 AM
You're right about not grinding it all at the same time. If it sparks - POOF! Shrapnel everywhere, including in you.
jj.inc says: Jan 2, 2011. 10:15 PM
can i attach a 2' liter bottle to my bike (ill find a way) and fill it with led fishing weights.
pastaking in reply to jj.incMay 30, 2011. 12:03 PM
Yes. It should work. Make sure you sand the weights first, to remove the zinc coating, or they could spark.
jj.inc in reply to pastakingMay 31, 2011. 5:58 AM
Is it bad that ours don't have a coating, (health wise) :)
pastaking in reply to jj.incMay 31, 2011. 11:07 AM
Kinda, yeah. The zinc coating could spark and detonate the powder. I'm sure zinc oxide (in the smoke if the zinc gets into the mixture) is not too good for you, either.
mediocrityandme says: Apr 10, 2011. 11:32 AM
I have to make gunpowder for a firework for a chemistry project in school.
Unfortunately, I don't have time to buy pure sulfur powder on the internet and have it shipped to me, so I bought Bonide Sulfur Plant Fungicide, which is 90% sulfur and 10% other unspecified ingredients.
Does anyone know how I would go about extracting the sulfur from the mixture?
spenfisher12 says: Dec 22, 2010. 4:04 PM
3 things 1 i have that same mill 60 bucks at www.cannonfuse.com 2 your tittle should say black powder and 3 you should send ppl to this wabsite for compositions and in compatable chemicals link
Quantinuim says: Jun 9, 2010. 11:25 PM
Just woderin but coudnt u just crush the potassium nitrite powder and sulfer with a hamer???
MajorBromley in reply to QuantinuimSep 8, 2010. 5:19 AM
itel make a spark and blow ur face off but sure
Quantinuim in reply to QuantinuimJun 13, 2010. 10:39 PM
Bananas hav lots of potassium in them any idea how to make a banana bomb?
uberdum05 in reply to QuantinuimApr 25, 2011. 2:03 AM
?
bombmaker2 in reply to QuantinuimJun 13, 2010. 5:46 PM
You could but the quality would be absolutly terrible.
Quantinuim in reply to bombmaker2Jun 13, 2010. 10:42 PM
Howfine a powder does the Potassium nitrite have to be?
bombmaker2 in reply to QuantinuimJun 14, 2010. 10:36 AM
To make a good gunpowder, the potasium nitrate would have to be a powder similar to sugar.
MajorBromley says: Sep 8, 2010. 5:16 AM
dos it still explode when lit in non closed contaner
LukeQuietus says: Jul 11, 2010. 8:16 AM
A few quick things. 1. Using the plastic and electric scale is fine for measuring the ingredients separately. It's when they're together I'd be careful. But plastic isn't too dangerous. In china in fireworks factories they have a metal cylinder everyone has to touch before handling anything to take the possible static charge from your hands. 2. I'd work outside. Seeing as Potassium Nitrate will give it's own source of oxygen a fire inside with this around would be impossible to put out. 3. Use stones in the grinding mill to avoid sparks and possible charges. Obvious really. Also I'd make sure the inside of the Ball Mill has no metal just in case. 4. Mix the three in the grinding mill with some boilng water. This will help the binding process. Afterwards use rubbing alchohol which has been chilled in a freezer for 24 hours to remove the water and then sieve, CAREFULLY. Remember that's a metal sieve there. Perhaps a coffee filter would be better... 5. Use extension cords for the Ball Mill. This will mean you can stand behind a wall to turn it on and off so if it does blow up you're nowhere near it.
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