loading

Did you ever think you could make liquid nitrogen in your own garage? This is an industrial process so how can an individual do this? Still doubt me? Intrigued? Read on.

As a lover of science I tried to think of a challenging project that was out of the ordinary. After going through the internet web and Youtube I realized that no one had made liquid nitrogen in his home. Yes, I did see some videos where some would use a Stirling Cooler from a cryorefrigerator and use this to condense nitrogen on the exterior of the cold-head. While one is making liquified gas, this is done using a prefabricated machine. I wanted to make the machine that liquefies the gas. Furthermore, a cryocooler has a very low production rate. You will only get about 500 - 1000ml per day. On the following pages I will walk you through the basics of how to build your own liquid nitrogen generator. Using easily obtained materials you can liquefy nitrogen or air. The unit cools to -320F in under 50 minutes. The production rate is about 350 cc/hr.

A full tutorial and plans are at http://homemadeliquidnitrogen.com This page goes over theory, thermodynamics and more detail on where to get components and how to build this. This Instructable serves as a general introduction to how this baby is put together.

I have just added a new web tutorial on how to make your own N2 gas from the air. I will add this as a new Instructable in the next few days. You can get a link for it at the end of this one.

I have also built a high-precision cryogenic digital LCD thermometer for this project, which you can buy for yourself. You can see how it compares with an Omega digital thermometer here.

Ok. The video above gives you a quick 3 minute overview of the project. At the end of this tutorial I briefly mention the PSA I made for making the pure N2 from the air for the generator. If you're ready for 320 degrees below zero we can begin...

Step 1: Overview

The liquefication generator has a few basic components. Starting in order:

1. Scrubber - This removes CO2 and H20 from the gas stream. Without this the water and CO2 would freeze and clog the tubing and valves

2. Filter - We need to remove any micro-particles that can clog our compressor valves

3. Compressor - This compresses the gas to high pressure. Two important factors are the pressure and flow rate. This project uses an oil-free scuba compressor delivers a pressure of 3500 psi at a flow rate of 3 SCFM (I jacked it up to 4 SCFM). It is possible to use a regular refrigerator compressor, but the production rate will be significantly reduced

4. Pre-cooler - This cools the hot, compressed gas before entering the cooling tower.

5. Regenerative cooling tower - Hot compressed gas flows through a counter-current system to cool the gas to cryogenic temperatures. Expanded, non-liquid gas returns to get recompressed.

6. Throttle - This is a needle-valve that enables a controlled expansion of the gas without losing the pressure behind it.

7. Baffle - This reduces the velocity of the expanded gas so it does not dissipate the cooled liquid into the gas-stream. It also provides a larger surface area for condensation.

7. Reservoir- This is the collection system that collects the gas. Heat exchange with the environment is minimal.

Above is a picture of an early version of the generator using a recycle can. Later you will see an improved version.

<p>What are the other possible uses for the Nitrogen produced other than filling up tires as you stated? The production of Ammonia could be the nest step forward using the nitrogen gas along with a source of electrolysed hydrogen to try and replicate the Haber process since it is such a clean usage for the Nitrogen.</p><p>I can almost guarantee noone has tried making an industrial Ammonia producer at home from natural products such as nitrogen and hydrogen gas. One of the main issues being the high pressures and temperatures associated. It would be a pretty cool project though...</p>
<p>There is a pretty good reason why you people have not tried that because it requires high pressure and high temperatures and is frankly stupid to try at home.</p>
<p>small minded people refuse to dream big and look at the bigger picture -</p><p>it was only a question for scientific perusement, there is no need to be insulted</p>
<p>i use liquid oxygen for scientific glass blowing. would you help design one for liquid oxygen/</p>
If I understand what's going on in this process just use the &quot;exhaust gas&quot; from the PSA instead of the N2
Can you adapt it to liquify NO2?
Could this make liquid hydrogen?
<p>In theory, yes. However, you would have to provide the unit with a gas mixture containing pure hydrogen. That seems like an added cost and danger factor that I wouldn't want to deal with. This system is relatively safe because the gases involved are inert under usual conditions, and the only comparable risk to a hydrogen explosion during liquid nitrogen production is a pressure buildup from boiling nitrogen.</p>
Ignoring the danger, an electrolysis device could provide the machine with pure hydrogen. Also you can liquify the oxygen.
<p>what would be a minimum pressure rating you would recommend? i have a higher volume fan but is only rated somewhere between 1 and 5 psi</p>
<p>HI I am an engineering technologist looking to build a hydrogen fuel cell and to use a system very similar to this to cool it. You say a refrigerator compressor would work. Would there have to be an oil remover between the cooling tower and compressor? Are we talking about a dry compressor? Running a couple of these in parallel is a bad idea? Thanks.</p>
<p>oil less compressor</p>
Where do you buy 13x molecular sieve quality zeolite? I keep seeing zeolite clinoptolite online and am not trying to buy the wrong stuff in bulk. Also I'd like to point out the person who tried to give you a grammar lesson on your homemade pressure swing absorption liquid nitrogen generator instructable..... &quot;Allude&quot; &quot;elude&quot; dude air is being split apart into basic liquid forms, cut the author a break on this 20 page instruction manual which was generously posted for people like us. Sometimes people forget what their reading, I don't think this instructable is called really cold grammar. I for one thought everything was extremely well written. Thank you for posting.
<p>if u want better zeolite...try zeo chem 12-07 lithium zeolite</p>
<p>ebay...i just built a oxygen concentrator and got the zeolite from ebay. </p>
<p>Would decreasing the volume of the entire system and using a compressor from a fridge increase efficiency so that It will not take as long to get to pressure? Would it also be possible to catch the pure O2 from the zolelite after it reaches saturation to then cool into a liquid form?</p>
Did I read you correctly? You're getting 30 liters per minute? If that's not a typo then that production is incredible. Is it correct?
<p>It says 350cc/hr. this is the same as 350ml/hr, or approximately 0.03 liters per minute. :)</p><p>This is still a rather efficient production rate for diy.</p>
I have a business opportunity for you. You could make a lot of money with me. Please contact me at barfknecht.air.force@gmail.com if you are interested. I'm talking multimillions
how can you be sure liquid oxygen isn't made and your house doesn't burn down in 4 seconds flat?
I have an oxygen analyzer that is reading 1% O2 for the liquid. I'm using 99% N2 for my gas.
what about using it for ac. is that a good idea?
<p>How much does this entire thing cost? I want to make one and I am fine using a smaller compressor, but would running it for that long cause problems?</p>
<p>This is awesome. I want to build one now. I don't have any reason to have it, but I'm sure I could find some. :)</p>
<p>could you use car brake pipe ( also 1/4 inch, but copper and seamed) for the coolers to replace the stainless steel? Its an awful lot cheaper</p>
<p>Check the manufacturer specifications on the line before considering it. Cars can see around 1,000 psi in their brake system. He specifies that this system can see 3,000 psi. I did a quick search and found 25' x 3/8&quot; zinc coated steel brake line for $25. It claims 16,000 psi burst pressure, but doesn't specify the wall thickness.<br><br>Trust but verify. The first time you load it up, expect it to catastrophically fail. You should do that anyways. One little manufacturing defect can make a rather large mess very quickly. By &quot;mess&quot;, I mean rapid disassemble of the unit and anything around it, including you.</p>
<p>car brake pipes are copper coated steel. The copper is to help prevent rusting</p>
<p>In the UK, car brake pipes are usually steel direct from the manufacturer. However, both pure (relative term) copper and cunifer (copper/nickel alloy) is available. I imagine these are available elsewhere in the world? I have friends in the USA who use both copper and cunifer..</p>
<p>I'm not familiar with this tubing. You first have to make sure that it can handle the pressure. Second, you want to make sure it is thin enough to readily allow heat transfer.</p>
<p>based on your title, i thought you were making a generator that ran on liquid nitrogen. maybe that can be your next project!! :)</p>
<p>That could be done. Look at Sterling engines and/or TEC/TEG (seeback and peltier) modules. They can make mechanical or electrical energy from temperature differentials. I would think that would be horribly inefficient, but it could do something. :)</p>
About what, would you say this cost...? Where did you find all of these parts?
Absolutely incredible. Thanks for sharing.
<p>I'd love to make this, but I'm unsure of how I could put this liquid N2 to work.</p>
<p>well, if the T1000 comes along, this'd be rather handy don't you think? :P</p><p>Hope this comment doesn't break posting rules! </p>
<p>liquid nitrogen is used in many shop/industrial applications. I need it for cryo-treating certain alloys, shrinking parts for interference fit, purging oxygen from containers. Freezing corpses...</p>
<p>i agree with u:)</p>
<p>I was wondering if this in the first steps scrubs/removes CO2 from the air why couldn't you use the CO2 as dry ice to help cool the gas in the pre-cooler?</p>
<p>In step 9 ...</p><p>&quot;Such a simple solution that alluded me&quot; should be &quot;Such a simple solution that eluded me&quot; ... in this usage, allude = &quot;to refer casually or indirectly; make an allusion (usually followed by to): He often alluded to his poverty.&quot; ... elude = &quot;to escape the understanding, perception, or appreciation of: The answer eludes me.</p><p>Otherwise, good project!</p>
<p>Thanks for the correction. The change has been made.</p><p>Jonathan</p>
Also, search for the word &quot;mute&quot; in your article. I believe you meant to use &quot;moot&quot;.
<p>wow!</p>
<p>Hi there, </p><p>I work as an engineer for one of the companies that makes Liquid nitrogen. I just want to point out there are some very serious risks with this type of equipment which even the professional companies sometimes fall foul of. My professional advice would be &quot;don't try this without proper chemical engineering training&quot;, but since I know you already are, here are some safety tips to consider:</p><p>* Never store liquid nitrogen or operate this equipment in an enclosed area, always ensure sufficient ventilation. Nitrogen is an asphyxiate with no smell. The only way to protect yourself is to operate outdoors AND wear a gas composition monitor to warn you if oxygen levels in the air fall below 19.5%</p><p>* Make sure the equipment is thermally isolated well as it reaches extremely cold temperatures and you may burn yourself if you touch it. Frostbite may also occur if you spill any cold product on yourself. Always wear full length clothes and insulated gloves.</p><p>* If there is any possibility of liquid nitrogen being trapped in a part of the equipment (due to closed valves or ice blockage), fit pressure relief devices. When the liquid warms and expands, it can cause an explosion if there is no escape path.</p><p> * Distillation columns take in a lot of hydrocarbons and nitrous oxide with the air. These components build up in the distillation still, and can cause an explosion when they react with the liquid oxygen in the still. Ensure you purge the liquid often enough to remove these contaminants.</p><p>*If you are running this in your garage (I know I told you not to), don't enter before you take an atmosphere reading. Make sure oxygen is between 19.5 and 22%. <br><br>* Make sure all the pipework and vessel is constructed from clean, oxygen-safe metal. During startup, the unit will produce liquid oxygen before it starts to produce liquid nitrogen. High concentration oxygen reacts with any organic contamination, and even metal can become a fuel source for a fire. Carbon steel is not an appropriate material, stainless steel, aluminium or monel is better. Definitely do not use rubber pipes, seals or oil based lubricants!</p><p>* There is a chance the atmosphere around the equipment will be oxygen rich, so take care to eliminate all sources of ignition, such as electrical switches, flames, static on your clothes, sparking tools and anything that gets very hot.</p>
<p>wow, glad to see someone who's actually &quot;in the know&quot; providing safety tips and not some armchair &quot;expert&quot; like i've seen in the comment section of a lot of 'ibles that had any hazards to them.</p>
<p>Helzcurrah</p><p>You know us so well, Thanks for the safety tips they may safe someone from great difficulty. You know like death.. all joking aside thanks for pointing out some of the dangers that can be encounterd with this. </p>
<p>Great instructable!!! </p><p>@ <a href="http://www.instructables.com/member/helzcurrah/" rel="nofollow">helzcurrah </a> Looking forward to seeing you do some instructables on related topics. I think adding a timed fresh air inlet fan to the &quot;garage&quot; to cycle out the undesirable product might be good. I Might be making one of these systems soon.</p>
<p>Where did yo get the tube bender. I cannot find a 360&deg; bender.</p>
<p>I may have posted the source on http://homemadeliquidnitrogen.com</p>
<p>Hi, can it be used to chill water for cooling purposes, i.e. air conditioning without compressor. also is it operating in closed loop so that the nitrogen is used over n over again, instead of being wasted. If anyone can come up with low cost cooling option there is a great market to be tapped.contact me on haiderbil@hotmail.com </p>