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How to "make" plastic

Step 6The science behind it

The science behind it
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  • 652px-Styropor_in_Mikroskop_mit_Polfilter.jpg
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Polystyrene is a polymer made from the monomer styrene, a liquid hydrocarbon that is commercially manufactured from petroleum by the chemical industry.

The chemical makeup of polystyrene is a long chain hydrocarbon with every other carbon connected to a Phenyl group.

Expanded polystyrene (Styrofoam) is produced from a mixture of about 90-95% polystyrene and 5-10% gaseous blowing agent, most commonly pentane or carbon dioxide.The solid plastic is expanded into a foam through the use of heat, usually steam.

Pure solid polystyrene is a colorless, hard plastic with limited flexibility. It can be cast into molds with fine detail. Polystyrene can be transparent or can be made to take on various colors. It is economical and is used for producing plastic model assembly kits, license plate frames, plastic cutlery, CD "jewel" cases, and many other objects where a fairly rigid, economical plastic of any of various colours is desired.

When Styrofoam is added to acetone (a common organic solvent) it very rapidly dissolves, making it look like it is disappearing. The melted plastic can be recovered from the acetone to make hard solid Styrofoam plastic (polystyrene). In other words, you don't actually make plastic you just transform an existing form of plastic. The acetone sort of serves as a molecular "lubricant" between the polymer chains, allowing them to slide around each other. The Styrofoam becomes soft, releasing the air bubbles trapped in the foam, and the polystyrene ends up as a soft blob in the acetone. When the blob is removed and the acetone is allowed to evaporate, it solidifies into a piece of hard plastic.

Their are two type of solvents, polar solvents and non polar solvents. Bio-plastics will dissolve in polar solvents like water, while polystyrene will dissolve in non-polar solvents like acetone.

Let's consider two solvents that are pretty different in their polarities in order to explore this topic. Water, which we said is a polar solvent, dissolves almost anything that is polar, such as salt and many other ionic compounds. Water can't dissolve everything, though. Try removing fingernail polish with water and you'll see what I mean. Acetone, a solvent with some non-polar properties, is commonly used to do that job. Acetone is an effective solvent for all sorts of non-polar substances.

The resin identification code symbol for polystyrene, developed by the Society of the Plastics Industry so that items can be labeled for easy recycling, is 6. However, the majority of polystyrene products are currently not recycled because of a lack of suitable recycling facilities.
Hence, even tough this is a petroleum based plastic, you probably are helping the environment since you reuse a plastic that would usually go to waste and that would take thousands of years to decompose.

source: wikipedia
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24 comments
May 28, 2012. 7:14 AMkwazai says:
adding gasoline is do it yourself napalm.
wonder if the 'coffe cups' make a better plastic with acetone than the 'packing peanuts' do?
Aug 27, 2011. 4:04 AMNagarok says:
Looking at the science behind it, you theoretically don't need to use acetone to make this react.

You just need a non-polar solvent that could be potentially less dangerous, but they may not be as readily available as acetone.
Feb 8, 2012. 4:17 AMsquiggy2 says:
I had this thought myself, but acetone is good because it evaporates quickly. I Made a test batch of this stuff about - 10-15 millilitres - using turpentine. It dissolved well enough, but 2 weeks later it's still squishy.
Nov 28, 2011. 7:04 AMde.das.dude says:
how is this for moulding PC case parts for mods? is this stuff hard to paint? my thoughts are solvent based paints should work.
Jan 24, 2009. 3:38 PMjmbudka says:
I want to try using this to create cheap custom plastic toys. Has anyone had luck pouring this material into a plastic mold? Obviously it is constantly getting harder as the acetone evaporates. But is the initial viscosity of the material light enough to be poured as a liquid? Or is it more like say: vaseline, or peanut butter or clay?
Nov 18, 2011. 6:56 PMwolfkeeper says:
You could try using polyester from fiberglass kits. It's quite brittle, but adding any fibers to it strengthen it enormously (paper or glass fiber) even in comparatively small quantities. It works out at about a penny a gram, plus the cost of the fibers.
Nov 17, 2011. 10:59 AMuseraaaaa says:
try hot gun glue...
May 1, 2011. 8:37 PMjpoopdog says:
none, its like thick silly putty. polystyrene requires massive amounts of solvent to completely dissolve , but just as bread becomes soggy with a few tablespoons of water, so does the polytyrene.

however, if layed intop of a mould, and in contact still with some solvent (gasoline or acetone), it should eventually seep intot he mould so long as the air can escape the mould as the polystyrene come in.
Apr 7, 2010. 3:21 PMsurvivletroop says:
it is like a clay but it can be put into a mold and takes the same prosses
Feb 5, 2009. 10:14 AMgunnk says:
I want to do the same. I've tried this technique, but so far I've found that I continue to have dissolved air trying to come out of the resulting styrene for days. It leaves the resulting styrene filled with bubbles. Looks like others here are having some success, so I need to try again.
Jun 24, 2008. 8:35 PMenergeej says:
I plan to try and make a custom holder for my MP3 USB Stick player to attach to my bicycle. I can't find any which will provide me access to the buttons while still holding it tightly. So I decided to see if I could make plastic and design one myself. This tutorial was great.
Nov 17, 2011. 11:03 AMuseraaaaa says:
amazon - InstaMorph - Moldable Plastic
Nov 18, 2011. 4:20 AM90mp11 says:
InstMorph = money

Acetone (nail varnish remover) and Polystyrene (scrap) are things most people have in abundance.

The Acetone may destroy the paintwork on the MP3 player, but doesn't copst anything to produce, and saves more plastic waste being sent to landfill
Nov 18, 2011. 6:31 AMmpilchfamily says:
You could always wrap the MP3 player in Saran wrap to protect it while the plastic dries.
Nov 17, 2011. 8:17 PMkemp101010 says:
This could be useful for making a custom screwdriver.
Nov 3, 2009. 7:23 AMbdelarosa says:
Okay so I really need help... Im trying to make a red hard plastic wig - i cant seem to find one online to buy so i have to make my own (im not the type of girl who gives up that easily!) kinda like this one
Nov 17, 2011. 11:02 AMuseraaaaa says:
or amazon -> InstaMorph - Moldable Plastic
May 1, 2011. 8:38 PMjpoopdog says:
actually, the kind of plastic hardhat, the really thin types you see in $2 shops, are made from pvc glue, allowed to dry in a mould, with some kind of colur in it.
though, polystyrene should work also
Feb 11, 2010. 11:15 AMcocodlicious says:
Try the beauty supply store you ca get a WEAVE!
Feb 1, 2011. 12:31 PMhughconley3 says:
So how much styrofoam does it take to make plastic, cu. ft. to cu. ft. ratio?
Dec 5, 2010. 8:51 AMvickibrvt says:
Most polish remover is acetone.
Dec 17, 2008. 3:26 AMsalec says:
This acetone stuff seems dangerous, especially if you are going to repeat this often (to make stuff). Also, we let it freely evaporate into the atmosphere without knowing what effect it has on it. Why cant we use controlled heat (e.g., an oven) to melt the plastic, instead of dissolving it?
Nov 11, 2010. 4:42 AMelectfire says:
You can't melt Styrofoam cause it burns easily and produces toxic fumes.
Also it doesn't burn in a predicable manner the flame will "worm" it's way through the Styrofoam until it runs out of fuel or the fumes cut of the oxygen to the flame.
(I found this out from experience by the way, at lets say I rather not repeat the results just in case I am not as luck this time as I was before... >
Nov 14, 2010. 1:17 PMsalec says:
Does it produce toxic and/or flammable fumes on temperatures at which hot-wire Styrofoam cutters operate?
Oct 23, 2010. 7:39 AMbeehard44 says:
so far acetone has no environmental impact except it can be toxic in huge quanitities (like if you pump a room with the acetone vapor) but normally acetone breaks down
Jun 12, 2010. 10:39 PMAustringer says:
As chemicals go, the big danger with acetone is fire, and after that removing all the oils from your skin. You actually make acetone as part of your metabolism when you run low on carbohydrates, so if it was seriously toxic or had a huge environmental impact, we'd all be pretty much out of luck.
Apr 23, 2009. 12:47 PMsharlston says:
you cant melt styrofoam because it gives of harful gasses
May 1, 2011. 8:33 PMjpoopdog says:
actually, your wrong
when you melt styrofoam, the bubbling that occures is just the tiny styrofoam bubbles popping, and those bubbles are just full of air that smells of styrofoam because it will have been trapped within the styrofoam for several years. but really its no more harmful than smelling warm plastic thats been left in the sun.

also

let this be known to all.

when your solvent evapourates, it will form small bubbles in the styrofoam, and unless the styrofoam is under some kind of pressure, it will refoam up again, sort of, most likely double in size from when it was gooey.

Apr 17, 2009. 8:15 PMSilver X Viper says:
http://www.instructables.com/id/HomemadePlastic/?ALLSTEPSBECAUSE you are not dissolving plastic. You are dissolving STYROFOAM to make plastic. If you want a less fumigating way to make plastic see this:

http://www.instructables.com/id/HomemadePlastic/?ALLSTEPS

It also makes moldable plastic but via melting things like shopping bags, gatorade & soda bottles, candy containers (Wrappers too?), that sort of stuff. However there is more of a chance you will make a mistake when using that method and depending on acetone used in this method it could also take longer.
Nov 21, 2007. 7:48 AMlancruz says:
Out of curiosity what have you created with your moldable plastic?
Mar 27, 2009. 10:46 AMpcdls says:
Great Instructable. You have to be a Deathnote fan. But why use Mello's callsign when you use the katakana for "L"?
Dec 29, 2008. 9:02 AMstevenpa says:
For some reason my styrofoam won't dissolve. You see the liquid go into it and it gets a little softer but nothing more. After 1 hour pushing the stuff only gets smaller but it doesn't dissolve. Are there differences in quality between some brands of aceton? I really want to make it work.
Feb 5, 2009. 10:09 AMgunnk says:
Using packing peanuts as your source? Some peanuts are now actually made from cornstarch and will dissolve in water. I haven't tried dissolving those in acetone, but it's possible you don't have real styrofoam but an "environmentally friendly" alternative of some sort.
Jun 20, 2008. 7:54 PMREA says:
will the plastic react in any way with plaster of paris?
Nov 6, 2008. 9:04 PMShane1163 says:
no I use it, I make molds and I mold stuff from the dissolved styrofoam with it
Aug 24, 2008. 11:24 PMshinde_tukaram says:
no. plastic does not react with plaster of paris
Nov 14, 2008. 2:09 PMred-king says:
wow... rofl
Jul 29, 2008. 8:10 AMjtc says:
Have you tried adding color to the plastic at all? If so, what materials do you use? If not, does the polystyrene solidify into a while plastic? What materials are you using for molding? Can I create a frame of cardboard, for example, and spread the plastic over it?
Jan 21, 2008. 10:26 AMSpectermonkey says:
Interesting...Very interesting. I just signed up for the site, today..And I must say I'm quite impressed. I've been using other sites like "tricklife.com" and the community there are a bunch of slack-jawed dirty-mouthed, chest beating 12-year olds, spewing obscenities and trying to look and sound a whole lot tougher and more belligerent than they are in person. This site is much better, and more civilized. People actually communicate like real human beings, instead of sending a bunch of obscenities and calling eachother "Fuk heds". P.s. I'm totally making some custom action figures with this stuff. Excellent instuctable Keep up the good work!

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