This is a short video of the full version. IN the full version we also cover more setup techniques and cover how to edit using adobe Photoshop CS. To take a look at the dvd go to the links below:
http://www.tubetape.com
http://www.markapsolon.com

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However - I'm not posting to quibble - I'm posting with a tip for what to do in this situation. Try reversing the image of the person! It's much harder to spot a hair parting on the wrong side of someone you don't know than it is to spot a shadow falling the wrong way :-)
regards,
G
Chroma keys are really only used in the film and video world, where it would be too time consuming to individually edit each frame of film or video (remember there are 24 fps in film and 30 fps in NTSC video) and remove and/or change the background. In this situation it is much faster to take the time during production to use a green or blue screen.
Also, in your example, the talent is blocked much too close to the green screen. If she were wearing a white or light-colored shirt, you would clearly be able to see a green hue to her shirt in the original photograph. When doing a key, this would cause her clothes to become opaque and look like a ghost. The green screen and the talent should always been lit entirely separately and the talent blocked at least 15 feet from the screen.
Also, the majority of this video seems to just be a plug for the software you're using and a way to increase traffic to your website.
Unless you want your camera angles changing much, most modern software doesn't require a CSO background. Take a shot of the background and without moving the camera insert the subject and take a second photo.
Photo 1: Empty background
Photo 2: Background plus subject
Photo 3: Substitute background
Whilst re-rendering photo 2, most software can recognise images from photo 1 and replace them with images from photo 3, effectively moving Photo 2's subject to a new location.
As filmnuts says, for a single image CSO is completely unnecessary, and even in video unless you need tracking you can also cheat your way out of it.