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How to Make Potassium Nitrate

video How to Make Potassium Nitrate
Make Potassium Nitrate from Instant Cold Packs and Potassium Hydroxide

Warning: This reaction will produce large quantities of toxic ammonia gas. Perform the reaction outside or in a fume hood. Potassium hydroxide is highly corrosive; wear gloves when working with it.

Some instant cold packs contain ammonium nitrate as their active ingredient and when mixed with potassium hydroxide will produce potassium nitrate and ammonia gas.

Get an instant cold pack that clearly says it contains ammonium nitrate, cut it open, and pour the contents into a container. If its unused there will be a water pouch that you can discard. The rest of the pack is ammonium nitrate. Usually its coated in an anti-caking agent so it'll be off-color.

If you're using an already used instant cold pack then filter out the liquid and let it evaporate until it's dry. The crystals will be ammonium nitrate.

Take 80 grams of ammonium nitrate and dissolve in 70 milliliters of hot water. This will take some time so be patient. It will take even longer in cold water so use hot water when you can.

If it has an insoluble anti-caking agent then you need to filter it off through a coffee filter.

Separately, measure out 56 grams of potassium hydroxide. Potassium hydroxide is sold online to make homemade soaps and for biodiesel.

Add just enough water to completely dissolve the potassium hydroxide.

When both solutions are clear and ready, add the ammonium nitrate solution to the potassium hydroxide solution. This step will produce large amounts of ammonia gas and must be done outside or in a fumehood.

Leave the solution in a very well-ventilated area (outside is best) for all the water and ammonia to evaporate. You can also boil the solution to dryness, just remember it is still producing ammonia.

Now you have potassium nitrate!

To test it, mix a small portion with an equal amount of sugar and set it on fire. Normally pure sugar does not burn but if the potassium nitrate works then it will flare up in a purplish pink flame.

You can also make sodium nitrate by substituting the potassium hydroxide for 40grams of sodium hydroxide and follow the same procedure as the video.

In an upcoming video we will show how to make sodium nitrate from ice packs and baking soda. This requires a slightly different procedure than this video.

Please visit our YouTube channel at: http://www.YouTube.com/NurdRage for other videos like this one.
49 comments
1-40 of 49next »
Oct 30, 2011. 12:44 PMlperkins says:
If you wish to make this from scratch with more primitive equipment and tools, check out "The Pirotechnia of Vannoccio Biringuccio" It's available on Amazon among other places.
Apr 20, 2009. 10:53 AMpyrofirelighter says:
ammonium nitrate is less reactive than potassium nitrate, making it less better for pyrotechnics, also it is hydroscopic: it attracts water. That means it cakes together and gets annoying. anyway, potassium is better to use.
Aug 11, 2011. 8:24 PMsniperHunted says:
ammonium nitrate is actually a pretty good substitute for potassium nitrate.
May 4, 2009. 6:14 AMTombini says:
KNO3 is very hygroscopic
May 7, 2009. 5:13 PMTombini says:
Thats weird, because my KNO3 if left outside turns into a puddle after 2 days, I live in Western Australia, the current humidity is 72% It may not be comparitively hygroscopic, but it still does trap enough water to become visually wet
May 8, 2009. 1:09 AMTombini says:
It was to demonstrate the hygroscopic nature of KNO3, all nitrates are soluble and most are hygroscopic and that was the first and only time I have ever left a chemical in the open
May 11, 2009. 1:17 AMTombini says:
No, not everything is hygroscopic Take for instance wax, it is in fact hygrophobic and will not dissolve in water nor absorb it from the atmosphere And no, I never implied that KNO3 is more hygroscopic than NH4NO3, but as they are both nitrates they tend to be hygroscopic. The bottom line is; KNO3 IS hygroscopic, this ties back to my original arguement
May 15, 2009. 3:13 PMTheDeviant13 says:
it means that the substance repels water
Jan 27, 2012. 4:07 PMcrusty1 says:
"Brilliant observation" but how could it mean anything if it does not exist?
May 15, 2009. 1:21 AMTombini says:
By saying that every chemical apart from water reactive chemicals will absorb some water from the environment is a contradiction to you previous statement; "In fact, for most environments, KNO3 is not hygroscopic. The relative humidity must be very high before it starts absorbing water." I would like you to clarify whether or not KNO3 absorbs water from the environment because in this statement you exclaim that for most environments KNO3 is NOT hygroscopic, of course I am assuming that by most environments you would include your own. Yeah, I didn't intend to make it sound like KNO3 is more hygroscopic than NH4NO3, if you look at my first comment I simply said; "KNO3 is very hygroscopic" basically a statement in itself. Oh, and I meant to use; "Hydrophobic" rather than "hygrophobic"
May 20, 2009. 1:59 AMTombini says:
I will have to break your wall with a Chuck Norris kick! lol I agree with most of what you have said although some of my comments didn't come out the way I would have liked, mostly being misinterpreted. Anyway the bottom line is; KNO3 is hygroscopic (insert big tick of approval) Just as long as you understand that my original point was to show pyrofirelighter that KNO3 is hygroscopic I will be contented (there have been many a time where my rockets have failed due to absorbing water.) By the way I love your comments on cheese and gardeners :)
May 21, 2009. 2:08 AMTombini says:
That is impossible, its like dividing by zero or the square root of -1!
Jul 4, 2009. 4:12 PMthoraxe says:
the square root of one is i
Jan 27, 2012. 4:13 PMcrusty1 says:
1
Jul 4, 2009. 10:31 PMTombini says:
But it still isn't a real numer is it?
Apr 16, 2010. 5:43 AMcritterfluffy says:
ah, I hate it when people say you cant divide by zero.  You can as long as you do it right and accept infinity as an answer.  x/0 = infinity(but not always). 
Examples:
0/0 = 1
infinity/0 has several answers
and any number divided by zero is infinity.

If the numerator is an equation than anything is possible.  Sorry about the response(expecially 9 months later) but I just hate that they teach this in school since it isn't technically true.

Maybe this should be my first instrucable.
Apr 16, 2010. 5:54 AMcritterfluffy says:
correction for above.  0/0 equals anything.  It has been a number of years since my calculus class so fuzzy memory.
Feb 10, 2011. 10:20 AMElectricHare says:
I found Potassium Hydroxide from Walmart as a drain cleaner. My KOH was about 97% and it worked really well in making Potassium Nitrate. It costed something like 6 dollars...
Aug 18, 2010. 2:34 PMweezybaby says:
Heyy, so the vid to make this at home isn't up anymore? But i was wondering 2 things?: 1. How long does it take for the crystals to become dry? Mine are still kind of slushy cuz theres water in it? 2. What do you burn stuff on? It looks like a paint can lid? Thanks
May 16, 2009. 5:15 PMJK452 says:
can u get the Potassium Hydroxide somewhere else besides the internet
Jun 14, 2009. 8:08 PMmacgyver603 says:
Are there any stores that sell it, like Walmart or Target?
Jun 9, 2010. 7:15 PMitsmanofpopsicle says:
But what if you want to explore the science and create crude potassium permanganate? Wouldn't you need potassium hydroxide?
May 16, 2009. 6:25 PMJK452 says:
do D batteries hav enough? if not how many do i need? also does the type of battery matter like duracel or energicer
Jan 30, 2010. 3:51 PMjames10101 says:
if i just boil the dissolved ammonium nitrate only will it produce ammonia gas
Jan 10, 2010. 5:24 AMgeonav1 says:
while i can definitely find uses for Potassium Nitrate, I can also find a good use for ammonia gas- it can be used to fill balloons & dirigibles.  =-)
Dec 17, 2009. 5:22 PMMichael Pawlicki says:
i probrobly shouldent have made this because its highly flammable but its TOTALLY WICKED
Nov 15, 2009. 7:09 AMThenwcp says:
Another thing people might be interested in is making your own potassium Hydroxide (KOH).  I'm sure you've heard of it but if not here's a source (even  though I hate wikipedia this is accurate).


http://www.wikihow.com/Make-Lye
Oct 14, 2009. 10:03 PMBOOM5601 says:
Couldn't you just make sodium nitrate by substituting the potassiumhydroxide with Sodium Hydroxide?
Oct 15, 2009. 11:42 AMBOOM5601 says:
Sorry, didn't see that.
1-40 of 49next »

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