Introduction: How to Test If Fertilizer Has Nitrates in It

In this video we show you how to test if a fertilizer has nitrates rather than urea or ammonia as its nitrogen source.

The idea is quit simple, in a strongly acidic solution the nitrates will behave like nitric acid and dissolve copper metal releasing nitrogen dioxide gas. Looking for this gas is a strong indication for the presence of nitrates.

WARNING: these reactions produce toxic nitrogen dioxide gas, this must be performed outside or in a fume hood.

To perform the test, simply mix some of your fertilizer with water to dissolve the nitrates and then mix it with hydrochloric acid. Then add in some copper metal.

The reaction is very slow to start up unless you heat it. A nerdy way of heating it on the spot without using a heater is to add a small ball of aluminum metal, don't use too much or it will go out of control. Stir the mixture as the aluminum dissolves to distribute the heat evenly.

After the mixture is heated, place a glass container over the mixture to keep the gases in. If nitrogen dioxide is forming the distinctive brown nitrogen dioxide will fill the container.

What's happening is that in the highly acidic environment (low pH) provided by the hydrochloric acid the copper is reducing the nitrates to nitrogen dioxide gas. This test is specific to nitrates but only works if you have a very high concentration of nitrates in your sample.

And that's how you can tell if there are nitrates in your fertilizer.

If you want to test for ammonia (in case you have ammonium nitrate) just mix some fertilizer with half as much sodium hydroxide and add a little water to cover it. If it starts bubbling and releasing ammonia gas then it contains ammonia.

Don't smell the gas directly, it's not safe. Instead, hold a wet piece of paper over it for a few moments and then sniff the paper. You'll be able to smell the ammonia without gassing yourself.

Note: Yeah i do know that there are hundreds of better tests for these substances. But this method is the simplest i could find that used stuff you could buy at the hardware/plumbing store.

Also, you can't substitute other metals like aluminum or iron because they will tend to produce colorless hydrogen with out without the presence of nitrates. Copper is the best metal to selectively produce nitrogen dioxide from nitrate (gold also works but you have bigger issues if you're trying to test nitrates using gold...)

Comments

author
Keiwie made it! (author)2017-02-02

Hi, I was interested in doing some research on nitrate concentration in fertilizer and was wondering what a heavy or light concentration of nitrates might tell us about the fertilizer.

Also, what might the pros and cons be of using nitrate as opposed to ammonia?

Just trying to gain some research knowledge, thanks!

author
KeithV10 made it! (author)2016-06-28

Now that we know there is nitrates. How would you go about measuring either the specific quantity and/or percentage per unit of volume?

author
Biopyro made it! (author)2009-05-06

I held my fingertips in some 100% dinitogen oxide in school once, believeing it to be safe. When I removed them my fingertips were completely yellow, which stained the skin until it died naturally! My fingernails were yellow for months although it did eventually fade.

author
NurdRage made it! (author)NurdRage2009-05-06

You sure it wasn't nitrogen dioxide? I never heard of dinitrogen monoxide having that particular effect.

author
ClownW made it! (author)ClownW2015-05-09

I have gotten Nitrogen Dioxide burns from distilation vapors but they have always been brownish red.

author
lemonie made it! (author)lemonie2009-05-06

Dinitrogentetroxide (NO2 dimer) is what he means.

L

author
NurdRage made it! (author)NurdRage2009-05-06

heh, Pretty awesome class if they had that stuff lying around. :)

author
Biopyro made it! (author)Biopyro2009-05-06

On Fridays we were able to carry out our own experiments. I was doing one regarding the amount of copper in pennies, so was dissolving them in concentrated nitric acid. Was pretty awesome!

author
NurdRage made it! (author)NurdRage2009-05-06

You got to pick your own experiments? You lucky son of gun. It wasn't until grad-school that i could do something of my choosing. At least the current science classes are more interesting than mine.

author
Biopyro made it! (author)Biopyro2009-05-07

It did have some purpose - we couldn't just test anything, but were limited to something which we could write a report on, which would give an analysable set of results. I was always led to believe that there was a lot more freedom for mild stupidity like this in the past. It certainly seems to me that kids have a lot less freedom because of health and saftey today than even I did! What age is grad school?

author
Biopyro made it! (author)Biopyro2009-05-06

Myyyy mistake! Yeah it was, clearly didn't read throughafter I wrote that.

author
minerug made it! (author)minerug2009-06-12

On the topic of stains- try silver nitrate This is a silver nitrate stain looks like after ages of scrubbing

DSCN2722.JPG
author
ClownW made it! (author)2015-05-09

Ok so I bought some walgreens instant cold packs I wanted to get a small amount of very pure ammonium nitrate. I mortored a few grams very fine and mixed with sugar to test it. It did not ignite with a flame.

So is this urea? Is there any other test?

author
Tool Using Animal made it! (author)2009-05-06

or, in Florida, you read the label as the law requires a percentage breakdown of each of the five types of nitrogen a fertilizer could contain.

author
NurdRage made it! (author)NurdRage2009-05-06

yeah, if you're in florida you're all set. A put up this instructable cause someone got some surplus fertilizer wholesale and some moron along the sales chain lost the documentation of what was in it. So the buyer asked me if there was a way to figure out if there was nitrate in it as opposed to urea. I live in canada and nitrogen percentage is required to be listed on fertilizer, but not nitrogen type.

author
dchall8 made it! (author)dchall82009-05-06

This is good if you don't have the bag. In the US the common fertilizer nitrates are ammonium nitrate, sodium nitrate, and potassium nitrate. You can almost expect one of those to be in chemical fertilizer. The label will list the percentage of nitrogen, potassium, and phosphorous and then tell you what the elements were derived from by chemical name. There are many chemical names in use for the same chemical formula so it is not quite a guessing game but close. The only issue with them that I'm aware of is with ammonium nitrate. The plants will use the nitrogen from the ammonia in preference to the nitrate. That allows the nitrate to leach into the soil and groundwater.

author
NurdRage made it! (author)NurdRage2009-05-06

Ah cool, interesting to know. Plenty of fertilizers over here that are Urea based, which have no nitrates. I hear in china that ammonium carbonate based fertilizers are common. I suppose my next task is to figure out a way to detect Urea :)

author
lemonie made it! (author)lemonie2009-05-06

Bacteria will convert urea to ammonia and ammonia to nitrate, fertilisers get a bit fuzzy when they're in the ground... Have you any thoughts on using biological (bacteria) tests on fertiliser? L

author
NurdRage made it! (author)NurdRage2009-05-06

biological tests would certainly be interesting. But excessively complicated, dirty, or tedious to perform reproducibly. Although if i ever come across a straightforward procedure I'll try to make a video for it.

author
lemonie made it! (author)lemonie2009-05-06

You know the old nitrate method of urine and horse-manure, bacteria are wonderful things - such as I'm at least thinking about whether I can develop a test of urea. Hmm

L

author
NurdRage made it! (author)NurdRage2009-05-06

oh, you want a test for urea. Now that i think about. There is an analytical chemistry technique where one builds a potentiometric sensor using urease enzymes, a pH electrode, and some chemicals. Can test for urea relatively quickly.

author
lemonie made it! (author)2009-05-06

To more accurately describe the test, you are using copper to reduce nitrate to NO2 - this is what makes it specific to nitrate.

L

author
NurdRage made it! (author)NurdRage2009-05-06

very true, i should have mentioned that part.

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Bio: NurdRage is a dedicate group of science nerds trying to further amateur science with direct how-to instructions in video format. We saw what was already ... More »
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