I should warn you that not only is the drink you're going to make extremely alcoholic (50-80 proof), but the base alcohol is so much more. Grain alcohol is also highly flammable, but I'm not going to get into that...
Edit*: Another instructable for some info
Step 1: Ingredients and equipment
Coffee, grounded just before making the coffee, enough to make 1 pint - Dark Roast
1 cup Grain Alcohol, 190 proof alcohol or 151 proof - typically goes by the name Everclear in the states. For our international friends this shouldn't be too hard to find as 190 proof, for Americans you typically will only get 151.
1/2- cup of raw Sugar or turbinado sugar, or if you want white boring sugar.
1 teaspoon vanilla extract
I will be using a Moka pot (Bialletti). Its typically an Italian coffee maker that makes something in between strong french coffee and espresso. Ideally you want your coffee as strong and as flavored as possible. Moka pots are fairly cheap ($20-$30) if you can find them. Bialletti makes sizes from 1 cup to 6. You'll be waiting awhile if you go with a 1 cup coffee maker, but a 6 cup coffee maker is tough to use for your morning shot.
You'll also need a large mixing pot, a pot for caramelizing sugar, and a coffee filter of some sort. Paper coffee filters don't seem to work well because the flow stops after awhile, so I found a reusable coffee filter that seems to work alright. The mesh may have been a bit too big though.