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Make Glass Mirrors With Silver Nitrate, Sugar, Ammonia and Sodium Hydroxide

video Make Glass Mirrors With Silver Nitrate, Sugar, Ammonia and Sodium Hydroxide
How to make a mirror silvering solution from silver nitrate, ammonia and sugar.

Glass surfaces can be given coatings of silver that make them into mirrors.

WARNING: Perform the whole experiment in less than two hours. This is because the solution generates highly poisonous silver nitride on standing. Also, the solution will give off ammonia when heated so you'll need to do this outside, in a fume hood or in a well-ventilated area. And wash away all chemicals with lots of water.

Get one gram of silver nitrate and one gram of sodium hydroxide. Then add enough water to both to completely dissolve them. Mix them together and youll get a black precipitate of silver oxide. Then add enough ammonia to completely dissolve the silver oxide. Add four grams of sugar and mix well.

The solution will deposit silver coatings when its heated. If you heat it in a glass container it will deposit silver on the inside of the container. To deposit it onto a glass pane you can put the glass into a tray with solution and heat the tray from below. But do not let the solution boil. Boiling tears the silver off the surface.

Thin layers of silver can be wiped off with a cloth if the silver goes where you don't want it. Thicker layers can be removed by applying hydrochloric acid.

This process produces a back reflective mirror, which is what most household mirrors are.

If you need to silver larger pieces of glass, or need thicker layers, just scale up the solution.
51 comments
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May 15, 2012. 7:31 AMrahaffasheh says:
Hello(:
Me and my friend are planning to do this experiment as a science fair project and need some help with the explanation..
So can you please give a scientific explanation for this experiment explaining the reaction and how the mirror is formed? (and maybe why we chose the materials that have been used..) anything you may now about it...?
We've been searching alot and can't find the right explanation..
please respond as soon as possible..
thank you (:
Apr 12, 2012. 3:55 PMoliverkellow says:
Hi, i just had a go at this process, with no success :(

I am trying to discern what part of my process was the least scientific!

1. I mixed the AgNO3 with Drain Cleaner (Sodium Hydroxide, with some unspecified filler, and aluminium granules which i took out).
It immediately went all grey and curdled, but not quite so dark as the solution in the video. I used tap water.

2. it dissolved back to a very slightly brown/clear liquid with the application of Ammonia (25% solution.. the best i could get)
I take this as evidence that the chemistry is going alight so-far..

so i put it on the hotplate (a glass container placed in Boiling water to cap the temperature) and it proceeds to go dirty brown and stay that way... twice in a row.

Do you think

A: the AgNo3 is off, its straight from a factory sealed test tube, what is its shelf life?

B: my shoddy sodium is not so strong OR it came with too much Aluminium and spoiled the reaction? maybe substituted it or, bound to the silver making the black murky result
C: Do i have to heat it harder faster longer- maybe the water diluting the ammonia took it a long way off from being a saturated solution, is that part of the plan or is it irrelevant??

Please Help! I am an amateur at chemistry :)
Apr 12, 2012. 9:40 PMoliverkellow says:
Oups, i forgot to WRITE that i added sugar... 4g as requested, well mixed.
Sorry.

I boiled a away for forty minutes, and got a oilslick like layer that came off on my finger.
Its hard to tell from the video timelapse, did you take an hour, or is it a 2 min reaction I should be expecting.
Does the fluid stay dark when the silver is all dropped out?

I was wondering if its worth doing all my remaining AgNo3 at once ´to get a thick shiny coat, or is there a saturation point relative to the Sodium Nitrate?

Thanks for the speedy reply!

Oliver
Feb 7, 2011. 8:15 PM7654321 says:
Server not found at nurdrage.com :(
Mar 5, 2011. 8:46 AMh0meIandsecurity says:
i noticed that too! it is still not fixed in other videos!
Mar 6, 2009. 11:33 AMPS118 says:
Is there a way to disolve the silver off an existing mirror to reuse with this method?
Aug 20, 2010. 5:46 AMwobbler says:
You don't need to use anything sophisticated or acidic, just metal polish and a bit of elbow grease. The metal layer is very thin and very easily removed with Brasso or similar, leaving the glass untouched. I used to make mirror photo-frames by masking off the mirror and rubbing away where I wanted it to be seen through to the photo at the back. (it was the 70's after all!- the 1970's that is, I ain't that old.) I've not tried this with acrylic mirrors though it may still work. If the silver is covered with paint or some protection, you'll need to remove this first before the Brasso will work. I used to just scrape it off with a razor blade. I don't think they'd invented paint stripper back then.
Jul 4, 2010. 6:54 AMmcshawnboy says:
Can you explain how to make "Front surfaced mirrors" used in kaleidescope building?
Mar 29, 2010. 10:58 AMbelgvr says:
Does it also works for chroming stuff? like plastic, etc...
Feb 22, 2010. 12:02 PMrufisdodd says:
Would it be possible to take the solution and pour it onto a large piece of glass?  Was there a time lapse in  your video or does the silvering start right away?  Thanks,
Nov 5, 2009. 3:31 AMMr. Apol says:
Does this coating conduct electricity? If so, it seems like an excellent way to make large Leyden jars . . .

Paul
Jul 31, 2009. 6:07 PMRotten194 says:
Cool experiment, but from what i read, silver azide is not toxic but is a very powerful force-activated explosive.
Aug 1, 2009. 6:16 PMRotten194 says:
Oh, thanks :D.
Toxic....muaw hahahahaha
Jul 29, 2009. 3:06 PMBlackice504 says:
Hi nurdrage i really enjoyed alot of your videos i will be watching all but i have a question for this chemi mirror can it be done on Metal Say to make a parabolic mirror? yes i know i would probley have to do something to the surface of the old Sat Dish but i would like to turn it into a nice mirror and i think this would be the best way any thoughts?
May 18, 2009. 9:55 PMajn142 says:
Wait, i'm curious. is i possible to do this on a plastic, such as plexiglass? or not? you say that its hard to do it without damaging the plastic, but since plexiglass doesn't melt until about 260 F, and water boils at 212 F, you would probably want to be heating the solution at about 200 F or below, right? would the plexiglass be damaged then? if there are any issues with my idea, let me know, i don't like to stay ignorant
Apr 29, 2009. 10:40 AMberndborn says:
does anyone know how to ad spots of color and the different colors to a fresh made mirror?
Mar 6, 2009. 6:56 AMmycroftxxx says:
This is a wonderful video for DIY projector makers. How easy/difficult is it for a hobbyist to acquire the needed chemicals?
Mar 5, 2009. 4:37 AMrimar2000 says:
Please tell me that this can be done on plastic. Any plastics: PVC, polyester, mylar, polycarbonate, etc.. I need it for a solar cooker. I am using glass mirrors, but they are too heavy.
Mar 5, 2009. 1:14 PMwobblestar says:
Sadly, it won't work on plastic. Cheers Mark
Mar 5, 2009. 6:27 AMNachoMahma says:
. A mirror silvered on the front should work better for a solar collector (if that is an option available to you).
. aluminized mylar might work, but probably won't be very rugged.
Mar 5, 2009. 9:21 AMrimar2000 says:
Front silvered mirrors are perfect for an optical and protected application. A solar cooker is permanently exposed to the elements: rain, sun, dust, dirt, and surface abuse. Aluminized mylar is too thin, I need some self-standing and stiff, as 1 or 2 mm thickness.
Mar 8, 2009. 7:09 PMKinnishian says:
What is this about conductive ink? Can I get that at a reasonable price? I'd be psyche to plate a frisbee with copper.
Mar 9, 2009. 6:05 AMrimar2000 says:
If it is possible to make it at low cost, with no much risk neither large devices, it will be very interesting for many of us.
Mar 6, 2009. 4:32 AMrimar2000 says:
My final design of mirrors arrangement for solar cooker contains 85 pieces, totaling 1 square meter. I could try that of the chrome/nickel plated. But, does not require a further thorough polishing? I was like two hours trying to polish an aluminum sheet and all I got was a negligible improvement. I need a mirror finish.
Jul 13, 2010. 11:25 PMmrwolfe says:
There are a couple of processes available that will put a chrome-like layer onto plastics. Chromed lamp housings and the like on motorcycles, for example, are typically not chrome plated at all but are "chrome" painted ABS plastic. One (but by no means the only) process is called spectra-chrome.

These processes are expensive to buy and set up, but not at all expensive to get done for you. From memory, spectra-chrome only costs a few dollars per square foot.  Google "spray chrome"

Probably a bit late for you now, given the date of your post, but getting a mirror finish on Aluminium is very possible.  I will be putting an instructable together very soon on polishing metals.
Jul 14, 2010. 3:51 AMrimar2000 says:
Never too late, thanks, very much. My solar cooker is hung at the rear balcony, waiting my free time for resume the mod.
Mar 6, 2009. 7:17 AMrimar2000 says:
Well, this seems interesting. Thanks very much.
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