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Make a Lithium Thionyl Chloride Battery

video Make a Lithium Thionyl Chloride Battery
How to make a Lithium Thionyl Chloride Battery capable of generating 2.8v with enough current to power a LED.

Warning: Thionyl Chloride is EXTREMELY toxic and this experiment must be performed in a fumehood by an experienced chemist with proper safety precautions.

Lithium thionyl chloride batteries offer excellent shelf life (sometimes over a decade) and energy density. Their main drawback is they are not rechargeable but for low power applications like memory backup they are extremely useful. At very low power levels, they can outlast the device they are installed in, making the recharge issue a non-issue.

As seen in this experiment, they are also extremely simple to make.

A solution of lithium tetrachloroaluminate in thionyl chloride serves as the electrolyte and the lithium and carbon rods are simply inserted in. The cell can produce up to 3.5volts depending on the purity and quality of the components. Our cell in the video used waste chemicals we had leftover around the lab so the voltage is not that high. But it did produce enough power to light a small light emitting a diode.

Commercial cells use lithium foil and spongy carbon for greater current but the concept is still the same.

If you like this video, check out our others at http://www.youtube.com/NurdRage
11 comments
May 24, 2009. 1:03 PMlemonie says:
Yea thionyl! One of my favorites, I'm sure I "Swerned" stuff with this... L
May 24, 2009. 1:25 PMlemonie says:
You're right, that's why I used "" - it's a variant. As I remember I sucked all the nasties down the sink with a water-pump, but Durham was like that... We also used to press our own sodium-wire - ever done that? L
May 24, 2009. 1:50 PMlemonie says:
Ah, but this was fresh, they seemed to think pressing it into the bottles of ethers would add dryness value, but I was never completely convinced as the stuff was pretty dry to start with and the stills didn't seem to last that much longer.

L
May 24, 2009. 2:10 PMlemonie says:
Aye, I'm sure the fresh wire is great too. Had a few fires when the younger ones were let loose with K... L
May 24, 2009. 2:52 PMlemonie says:
You do get a high surface-area to volume, and if you don't mind pressing it, more surface-area quicker. But if the ether's fairly dry, and you're going to dry it in a still anyway, and then have to get rid of the sodium-wire the value is questionable.... L
May 24, 2009. 1:31 PMBiopyro says:
What are the half reactions at the electrodes? Good explanation about it otherwise :)

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NurdRage is a dedicate group of science nerds trying to further amateur science with direct how-to instructions in video format. We saw what was already online and we thought "we could do better"... s...
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