Mokume gane is a technique that joins dissimilar metals together for ornamental purposes. Metals are joined by diffusion bonding to create striking contrast and patterns. There are hundreds of different metal combinations, patterns and techniques to choose from. I chose a textured combination of 14kt red, yellow and white gold. Because all these metals are relatively inert, it provides a comparatively easy example.
I have no formal or informal training in jewelry or silversmithing. However, I have done some blacksmithing, and I study materials science. Don't let that scare you! I will explain the theory behind each step, how to do it, and what to do if things go wrong. You don't need any previous experience to get this right.
This instructable is based loosely on the website I made to catalog how I made the wedding rings. The wedding site reads more like a story than an instructable, which is why I've restructured it for you. You can find the original here: http://www.mike-short.com/MnM/Rings/Rings-Intro.shtml
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Signing UpStep 1: Overview and Materials List
1) Make a billet of mokume gane from starting metals.
2) Cut, roll and shape that billet into strips for making rings.
3) Form these blanks into rings, solder them together and size the rings.
4) File, shape and polish the rings to a mirror finish.
There are many intermediate steps inside each major part.
Here is a list of tools and materials, along with links to buy them and prices as of February, 2011. I've split the materials into the four major parts. The entire project takes a couple weeks to finish, and each of the four parts can be done on its own with a long break in between. The materials list is a bit long, but having the right tools for the job makes it go far more smoothly. The total cost for the project with prices from Feb. 2011 is $2,168.30. Of that total, $1,719.00 is the gold metal, while the remaining $449.30 gets you all the tools, supplies and safety equipment to finish the entire project. Finding or borrowing tools and supplies substantially lowers this cost.
*Note: You can substantially lower the cost of this project by using different metals, such as silver, copper or brass.
Safety Supplies (Safety First!!!) (Total cost - $36.51)
(1) Safety glasses with side protection
http://www.riogrande.com , P/N 201708, $8.20
(5) Pairs of nitrile (blue or purple) gloves
http://www.vwr.com , P/N 414004-441, $12.62
(1) Lab coat or other long sleeve expendable clothing
$0, just use an old long sleeve shirt
(1) Plastic face shield
http://www.mcmaster.com , P/N 5481T28 , $15.69
Part 1 - Starting Metals (Total cost - $1,719.00)
*Note: The prices of gold change by the day. Check a reputable metals site, such as http://www.kitco.com for current prices.
(2) 1" by 1" sheets of 14kt white gold
$348 (Feb. 2011) x 2 = $696.00
(2) 1" by 1" sheets of 14kt yellow gold
$348 (Feb. 2011) x 2 = $696.00
(2) 1" by 1" sheets of 14kt red gold
$348 (Feb. 2011) x 2 = $696.00
Recovered dust & scraps
(-$369.00, adjusted to Feb. 2011 prices)
Part 1 - Supplies for Mokume Billet Making (Total cost - $158.65)
(1) Senpak heat treatment bag, 8" x 10"
http://www.mcmaster.com/ , P/N 3438K14, $9.35
(2) Pounds of dry WOOD charcoal, not briquettes!
http://www.acehardware.com or local hardware store, P/N 8231144, $7.49
(1) Small container of acetone
Local hardware store, ~$10.00
(2) Steel plates, 4" x 4" x 1/2" thick
http://www.mcmaster.com , P/N 6554K321, $34.32 for a 4" x 12" x 1/2" piece
(4) 5/16" to 7/16" hex head bolts, 2" to 3" long
http://www.mcmaster.com , P/N 91247A320, $10.03 for a 25-pack
(4) Matching nuts for the bolts above
http://www.mcmaster.com , P/N 95505A614, $8.66 for a 100-pack
(8) Matching washers for the bolts above
Local hardware store, ~$1
(1) Bottle of White-Out or Liquid Paper
Local office supply store, ~$2
(1) Piece of firebrick or insulating material to use as a heat-resistant surface
http://www.mcmaster.com , P/N 9355K2, $8.62
(1) Propane torch (not MAPP gas)
Local hardware store, ~$25
(1) Pair of tongs, strong metal tweezers, needle nose pliers or other tool for picking up hot metal
http://www.mcmaster.com , P/N 7379A24, $7.18
(1) Bucket of water for quenching (fast cooling)
Found $0.00
(2) Wrenches for tightening nuts & bolts above (I like adjustable wrenches)
Local hardware store ~$30
(1) 1/2" drill bit
Local hardware store, ~$5
(1) Glass or pyrex container, with a capacity of 100mL to 250mL
Found, ~$0
Part 1 - Access to Big Machines for Mokume Billet Making
-Furnace (must be set to 100°F (~55°C) lower than the lowest melting point among your metals)
-Vise
-Drill Press
-Bandsaw
Part 2 - Supplies for Making Ring Blanks (Total cost - $87.70)
(1) Piece of 180-320 grit sandpaper
Local hardware store, ~$2
(1) Piece of ~600 grit sandpaper
Local hardware store, ~$2
(1) Jeweler's saw
http://www.riogrande.com , P/N 110131, $11.00
(12) #2 jeweler's saw blades
http://www.riogrande.com , P/N 110101, $17.50 for a pack of 144
(1) Stick of jeweler's saw lubricating wax
http://www.riogrande.com , P/N 117003, $5.25
(2) 1" x 1" pieces of sturdy cardboard
Found, $0.00
(1) Pair of calipers or very precise ruler
http://www.riogrande.com , P/N 115189, $27.00
(1) Metal hammer (see below) or rolling mill
http://www.riogrande.com , P/N 112530, $22.95
Part 2 - Big Machines for Making Ring Blanks
-Vise
-Rolling mill (optional), hand-cranked or powered
Part 3 - Soldering and Sizing the Rings (Total cost - $162.44)
(1) Box of Rio-Pickle pickling agent for non-ferrous metals
http://www.riogrande.com , P/N 5010233, $11.25 for 3 lbs.
(1) 16 oz. mini Crock Pot
http://www.riogrande.com , P/N 501012, $19.25
(1) Thermometer (just has to go to 212°F (100°C))
http://www.mcmaster.com , P/N 6182K14, $13.96
(1) Box of baking soda
Supermarket, ~$3
(1) Glass stirring rod
http://www.mcmaster.com , P/N 8496K12, $1.77
(1) Bottle of gold & silver liquid flux, 1 pint
http://www.riogrande.com , P/N 504006, $8.95
(6) Inches of MEDIUM grade, 1/16" 14kt yellow gold wire solder
http://www.riogrande.com , P/N 600857, $20.76 (as of Feb. 2011)
(1) Propane torch
Use the one from Step 1, $0.00
(1) Bucket of water for quenching
Use the one from Step 1, $0.00
(1) Mandrel with ring sizes
http://www.riogrande.com , P/N 112367, $26.50
(1) Plastic or neoprene hammer
http://www.riogrande.com , P/N 112800, $47.00
(1) Metal cross-peen hammer
Use the one from Step 2, $0.00
(1) Medium size hand file
Local hardware store, ~$10
(1) Kitchen measuring cup
Your kitchen, $0.00
Part 3 - Big Machines for Soldering and Sizing the Rings
-Vie
-Somewhere with ventilation
Part 4 - Finishing and Polishing the Rings (Total cost - $4.00)
(1) Medium size hand file
Use the one from Step 3, $0.00
(1) Small needle file
Found, $0
(1) Propane torch
Use the one from Step 1, $0.00
(1) Bucket of water for quenching
Use the one from Step 1, $0.00
(1) Mandrel with ring sizes
Use the one from Step 3, $0.00
(1) Plastic hammer
Use the one from Step 3, $0.00
(1) Metal cross-peen hammer
Use the one from Step 2, $0.00
(1) Piece of 180-320 grit sandpaper
Use the one from Step 1, $0.00
(1) Piece of ~600 grit sandpaper
Use the one from Step 1, $0.00
(1) Piece of ~1200 grit sandpaper
Local hardware store, ~$2
(1) Piece of ~2400 grit sandpaper OR rag and stick of rouge
Local hardware store, ~$2
Part 4 - Finishing and Polishing the Rings
-Vise
-Lathe (optional, but saves a LOT of polishing time)





























































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Question on the measurements, though...I started with a billet approximately 1"x1"x0.24" (six 1" squares of 18ga metal) and after reducing its thickness to about 0.17" I haven't really extended the billet very much...my planning calculations indicated that I should have a blank that's about 2.3" long but it's still only about 1.2". Am I on the right track, or did I miss something?
Also, you say to repeat the process of reducing thickness and extending length until the billet reaches the dimensions from the planning step...is that correct? should I get the billet to be the final size in this step before increasing the layers? Once I increase the layers the billet will double in thickness and halve in width, won't it?
Oh, and I guess I should ask if I'm supposed to be making the billet both wider and longer in this step, or just longer? I've been hammering along one axis only so far and that's made the billet slightly longer but yet much wider.
Thanks again. I'm really having fun with this project.
I think you're on the right track. Copper is indeed tougher to work with than gold, since it work hardens faster and therefore will crack more easily. Gold is totally the best!
And as for the billet sizes, keep in mind the assumption of constant volume for your billet. If it's 1x1x0.24, then you've got 0.24 cubic inches of material. If you reduce the thickness to 0.17", you still have the same volume of material. If you assume all the length extension goes into one dimension, then you would have a billet that's 0.24"/0.17" = 1.41" long and 1" thick. In reality you get some expansion in both dimensions, so if you assume your billet has become 1.1" wide, and it's 0.17" thick, then it would be about 1.28" long. I hope that makes more sense in terms of conserving constant volume.
The reason I say to get the billet down to final dimensions before halving is that it's easier to deal with a thinner billet than a thicker one. If you halve the billet and start rolling it, you'll have to go through more steps and more hammering than if it's thinner.
Finally, as to making the billet wider/longer, that depends on the ring blanks that you want to cut out. I don't think it matters too much at this stage, especially if you just have flat layers. If you already have patterns then you have to think about how you want them to deform.
Keep the questions coming, I'm more than happy to help out!
Cheers,
-Mike
- Use a file, not sandpaper to clean up edges after baking/cutting billet
- Use cross-peened end of hammer to extend billet, but use broad face and gentler strikes as you get close to the desired thickness to minimize metal loss when grinding billet smooth
- Form the blank around the mandrel then place it in the vise to get the edges aligned well for soldering
- Use a thicker ring blank to give more leeway for shaping the ring so it's not so flat
I'll post more things that I discover as I come across them.Speaking of the rolling mill, actually, a friend whom I'm keeping abreast of my progress keeps pressing me to try to find a rolling mill that I can access because it will save much time and grief (which is probably true). Another friend who was an apprentice jeweler mentioned that this kind of application might damage a rolling mill, though, and I'm curious if you had any light to shed on that possibility.
I agree with your hammering the texture after dremeling, since that gives you finer spatial control over deformation at every location on the ring. Rolling that could lead to uneven thicknesses, or even side-to-side warping.
I'm curious what gauge sheet metals you recommend starting with and also how much I need to worry about elements that only show up in small amounts in my metals forming eutectic alloys that I need to worry about.
Thanks!
Sorry I didn't get a chance to respond to you earlier! I started with 18 gauge sheets of gold, and I wouldn't worry about very minor elements. They won't change temperatures that much in most cases. If you stay 50-100F below the melting point then you've got a bit of margin, while you'll still form a nice diffusion bond.
Also, if you run the bond for a while and it doesn't take, you can always keep cooking it for longer (provided your metals are cheap), and try different combinations of time and temperature.
You can certainly start with thicker metal; just keep in mind that you'll have more rolling to do. You'll also cut through fewer layers for the same depth of cut. It's all about how bold/fine you want your patterns to be in the end, and at what stage you apply deformation(s).
Finally, bonding for a long time will cause your lines to become a bit blurry and diffuse. You may be going for this, though a lot of what makes mokume look nice is just how crisp the lines are. I usually go for the minimum necessary to ensure a good bond, so my lines stay nice and sharp.
Also, check out the next set of wedding rings I just finished:
http://www.mike-short.com/Art/2012_08_02_JoseJaneRings/
These were one-hour bonds using 80/20 silver and 14kt white gold. I had 10 sheets of each, using 14ga. silver and 18ga. gold to even out the weight percentages. Much of the patterning was done after significant rolling, so more layers would be cut through. This one had hemispherical pits drilled using a ball end mill, to get the 'knots in wood' effect.
Cheers,
-Mike
Can I run my bond at a temperature 50-100°F cooler than the melting point of a 41%-Zinc alloy, or do I have to worry about higher concentrations of zinc forming or something?
As for diffuse vs. sharp bonds...I shall have to experiment to see what I like. A lot of mokume is a bit too bold for my tastes; one of the reasons I really like your wedding bands is the subtlety of the pattern. I'll have to play around with it a bit.
Thanks for the help!
~Kyle Marsh
- I'm considering buying a glass fusing kiln to use as the furnace. I see that 14k golds have melting points somewhere around 1800°F, and a full fuse for glass operates around 1700°F, so I think that a kiln capable of 1800-2000°F should work; am I correct in my thinking, or is there something else that I need to consider?
- You mention that the torch used for annealing and soldering should be propane, not MAPP gas...why is this important? Is it temperature, or will MAPP react poorly with something? I picked up a dual MAPP/Oxygen torch for cutting, brazing and welding figuring that it'd work, but if not I can return it and find something else.
- For practicing with less expensive metals I expect the metals to have substantially different melting points; I'm guessing that I need to do my diffusion bond at 100°F cooler than the lowest melting point of the mix? should I make time adjustments to account for this?
Thanks! This is a fantastic instructable and a great project.Thanks for the compliments, and the good questions! To answer them in order:
1) I think your kiln will work OK, as long as you can control the temperature to within about 25F. You want to keep the temperature about 50-100F below the lowest melting point alloy that will be formed. To find this you need to look at "binary phase diagrams" for each combination of elements in your golds (just Google these). Check or ask for the compositions of your 14kt golds; not all are the same. Sometimes you can't just go with the lowest melting point metal, because a lowe-melting-point "eutectic alloy" can form. If you need help interpreting these binary alloy phase diagrams, just ask.
2) The reason I suggest using propane instead of MAPP is because the flame is cooler (relatively), which gives you more control over the heat throughout the billet. MAPP can cause the outside to start to melt, which looks like the billet is "sweating." This means that you'll have no layers where melting occurs, and you'll partially ruin your pattern. You'll have to heat for longer with propane, but the billet will heat more evenly.
3) Again, see #1 for an explanation on picking the right temperature. I have used silver and gold together, which have very different melting points. I picked a temperature about 75F lower than the temperature of the eutectic alloy formed between gold and silver.
Good luck to you! I'm working on another set of billets, and I"ll be sure to post pictures soon.
I've also got a question about what parts of the diagrams I have to worry about are. For instance, looking at the Cu-Zn diagram, the lowest melting point is pure zinc down around 775°F, but my metals have at most 60% Zinc (where the melting point is all the way up at 1500°F). Do I only have to worry about the highest concentration of each element within my metals, or do I have to take the entire range of concentrations into account for every elemental combination? What about those trace elements?
Finally, what gauge of metal do you use to make your billets? Should the overall stack of metal be approximately the same thickness that you want the ring to have? 25% thicker? Twice as thick? I know there's a step to roll or hammer it out to the right thickness, but what's a ballpark number to shoot for?
Oh, and regarding patterns...I haven't looked this up yet, but I'm guessing the longer you let the diffusion bond go for, the more gentle your final pattern will end up being? As in, a short bond would keep the layers pretty distinct and I'd get sharp contrast in the final pattern, but a longer bond would let the layers blend into one another more gradually resulting in a more subtle appearance. Am I on track with that, or am I chasing a red herring?
Thanks!
I figured that heat might have been the issue with a MAPP torch. And mine has a nice fine tip for cutting, too. I'll go back and get a propane torch instead; sounds like less to worry about overall.
Thanks for the advice! I'll make sure to share thoughts and pictures as I progress!
If you have a rippled surface I imagine you'll need to find some way of making the faces you're mating perfectly flat before setting up for another diffusion bond? Is that taken care of in the grinding after you extend the billet?
You can certainly use a hammer, imparting a rippled texture to the layers. You will have to ensure near-perfect smoothness between layers before rebonding, which I would do by grinding/polishing your billet flat after hammering. I actually used a hammer to impart some texture after the ring was formed, on the mandrel. I basically hammered all over the surface and then polished it smooth, leaving a diagonal ripple pattern on the surface. You can even do things like drill hemispherical holes and then roll it flat, or punch holes and grind it flat to make concentric rings. Check out patterning techniques for Damascus steel if you want to see other ways of patterning mokume, and good luck!
"Note: You can substantially lower the cost of this project by using different metals, such as silver, copper or brass."
Nickel-silver, sterling silver or bronze would also work very well. That would also lower the cost of the solders used, bringing the cost of the project from the $2,200 range to the $400 range. That number goes down more if you can find/borrow tools from friends. If you can scrounge just a few things, like the sandpaper, steel, nuts & bolts and a hammer, you can bring it down to around $300.
A much better metal for a lower cost than gold is sterling silver.
Thanks
/Joe
First, I'm intrigued by the Japanese names for the smithing techniques you used (moku means wood, gane comes from kane, which means money (originally made from precious metals), etc). The Japanese do many things exceptionally well but I wasn't aware that their precious metals smithing techniques were that well known outside of Japan. I presume that other countries have their techniques as well?
Second, I bought my own wedding bands in Japan 24 years ago and they have two layers, platinum and gold, with the platinum layer outside and a somewhat wider band of gold inside. My ring turned out to be slightly too big for my left ring finger so ever since our wedding day I have worn it on my right ring finger on which it fits just fine. I tried to have it adjusted but was told that the metals have different melting points and cannot be resoldered once they are cut for resizing. Yet you carefully detailed a technique that solders multiple layers of dissimilar metals without any problem. Am I missing something here?
You make a lovely couple, by the way. I wish you both much joy and happiness!
Then, there are swords from the Middle Ages made from similar-looking Damascus steel blades (from the Middle East) and "damascened steel" blades (from Toledo, Spain). Today, there are "archeometallurgists" studying ancient forged blades to actually sort this out.
And of course, your non-lethal, hand-forged gold is quite gorgeous! Thanks for sharing the experience with us.
You're right on the Japanese name - moku=wood, me=eye,see and gane=metal,money. I'm not sure when mokume hit the international scene, but I don't see it as often as I'd expect to, even nowadays.
And as for your rings from Japan, they are correct that cutting (to resize) and re-soldering would be difficult. I made a diffusion bond, which was made possible because my metals could be held together at a very high pressure. Flat sheets or squarish billets are perfect for that sort of setup. I don't know if one could hold two ends of a ring together to make a strong diffusion bond. In addition, platinum melts about 700C higher than gold, and I don't know if gold solder would wet platinum metal.
Finally, with some metal combinations (luckily not Au-Pt) you run the risk of melting a eutectic alloy that forms between the two metals. This is an alloy with a lower melting point than the original two metals. Many solders are made this way, so that they melt at lower temperatures. Part of the reason I used all 14kt golds is that making a eutectic alloy at the interface wasn't a concern.
They also told me that it was unlucky to cut a ring after it'd been forged as that could symbolize the eventual breakup of the relationship so it was best that I not pursue it. Sage advice, I thought.