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It can not be just a molten salt. It has to be sodium chloride. If you pour other salts some explode but most do not.

It is not sodium. If you drop hot molten sodium into water it flashes and violently reacts with water but does not quite explode like the molten sodium chloride.

It most likely is not a chemical reaction but rather a physical one. If you check the PH after explosion, water is still neutral PH.

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