If you are genuinely interested in skulls but need some basic knowledge, I recommend buying this book. A Key- Guide To Mammal Skulls and Lower Jaws is an excellent book that will inform you about skulls and identifying them.
Step 1: Materials
A jar (or other receptacle that is relative to the size of your skull)
A good razor blade
Gloves (or in my case, plastic bags)
Your specimen (duh!)
Face mask (optional but useful)
Crazy glue (if you plan on fixing your skull in a position)