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The ferric chloride will not reach the copper because of this invisible layer.
Did you encounter this in your experiments, and if so, what did you do to get past it?
Do you use the "air assist" on your Epilog? I haven't tried this yet, but I'm wondering if the film you're seeing could be paint vapors that are re-settling on the piece after the laser moves away. If so, and if mashorter is using the "air assist" and you aren't, then the "air assist" may be blowing his vapors away before they have a chance to settle. Just a shot in the dark but I figured I'd throw it out there.
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