Here's a handy little tip to get those rims shining like new!, PLEASE FOLLOW DIRECTIONS EXACTLY THEY ARE VERY IMPORTANT OR DAMAGE MAY OCCUR
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Signing UpStep 1Preparation
1.) Rubber Gloves
2.) The Works toilet bowl cleaner
3.) Baking Soda
4.) Teaspoon
5.) Spray bottle
6.) Toothbrush (or other small brush)
7.) Small glass or ceramic bowl
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If your solution is too weak (unlikely, unless you have a European car that has not had the wheels cleaned in the last 5 years) you can increase the concentration, but I believe that if you need to go higher than 4:1 Water:Works and scrub with a wheel brush and your wheels still don't come clean, nothing will clean them without damaging them (yes, I have burned painted wheels with acid, it's not pretty). If you have cheap polished aluminum wheels (American Racing for example) DO NOT DO THIS! Acid on unpainted aluminum wheels = really ugly wheels and a big headache. If you have REAL CHROME PLATED STEEL wheels you can be far less careful with this procedure.
This works so well because as Ohm said, acid dissolves oxidation and most wheel gunk is oxidized brake-dust.
If you do somehow manage to screw this up and you damage your wheels, look up "Alloy Wheel Repair" in the phone book. You can usually get wheels repainted for a pretty reasonable price (compared to buying new wheels).