Sponge + Ferric Chloride Method -- Etch PCBs in One Minute!

Sponge + Ferric Chloride Method -- Etch PCBs in One Minute!
In this Instructable, I will show you how to etch a circuit board with about a tablespoon of ferric chloride etching solution and a 2 inch square sponge. You will be amazed as the exposed copper on the PCB disappears before your eyes, and your board is completely etched in a minute or less!

I found a passing mention of this technique of using a sponge with a small amount of ferric chloride on the Pulsar web site, and I was very skeptical that it could possibly work. So naturally, I tried it.

Whenever I have made circuit boards in the past, I did it just like most of us do. I put the ferric chloride into a small tub, dropped the masked circuit board into the solution, and rocked it back and forth for a long time. Even with fresh, strong ferric chloride solution, it would usually take at least 10 minutes for the copper to be removed. As the solution grew weaker, the etch would take longer and longer.

A few months ago, I discovered the 1-part pool acid (muriatic acid) to 2 parts hydrogen peroxide method of etching a circuit board. You will find lots of wonderful Instructables on this method. That method works great, and it made me mad that I spent so much money and effort with ferric chloride over the years when I already had all the chemicals I needed right at home to use this method. The down sides of the acid and hydrogen peroxide solution are that the muriatic acid can cause skin burns and is a little dangerous and damages things that it contacts. Also, I found the etching solution to be quite aggressive which was great for fast etching, but I ended up with severe undercutting and partial obliteration of the traces, and the solution tended to be more corrosive to the resist materials I used, and partially dissolved the mask away during the etch.

This weekend I tried this sponge and ferric chloride method to etch 3 Arduino shield boards I am prototyping for our RFID-enabled member access system at TechShop (TechShop is the 15,000 square foot membership-based DIY workshop with locations in Menlo Park CA, Portland OR and Durham NC). I was so impressed with the success of this technique that I decided to write it up as an Instructable.

The method I will now show you gives you the advantages of all the other methods, and none of the downsides. Specifically:

o You get a fast etch (much faster than either method I know of),
o You use a tablespoon of solution, so disposal problems are eliminated
o A small bottle of ferric chloride will last for hundreds of boards
o No tank or tub is needed, no heating or agitation
o Undercutting is practically non-existent, and the resist stays in place
o There is no need to try to reduce the amount of copper being etched
o The etch is so fast that it is actually exciting to watch and show your friends!

Let's get to it, shall we?
 
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Step 1What You Will Need

What You Will Need
You don't need a lot of supplies for this Instructable, just the following:

o Ferric chloride (available at Radio Shack, 16 oz bottle for $10, part number 276-1535)
o Sponge (2" x 2" square, cut from any sponge, or paper towel will work too)
o Rubber Gloves (you don't want to stain your hands)
o Copper Circuit Board (one or two sided)
o Cup of water (to drop the etched board into to stop the etching)

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213 comments
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Apr 29, 2011. 9:48 AMBarnaby Walters says:
Whilst this looks great for most boards, I would not recommend that you use it for boards with permanent marker resist — I just tried, and it wiped some of the marker off! I quickly changed plan and used the tub method.

Regardless, it was my first ever PCB and it's not too bad, I think!
Nov 28, 2011. 10:44 PMAgent24 says:
Forget the permanent markers, get a proper 'Dalo Pen' for PCB work instead.

I use mine for touching up toner transfer on the occasion there is a hole or some other problem.
May 19, 2011. 5:13 AMNick_F says:
You could also give a try to a German permanent marker (the red one only!), called Staedtler Lumocolor. They have a few different sizes. An image of these markers can be seen at http://www.jp.staedtler.com/upload/318_2_420_16611.jpg

Regards,
Nicolae
Apr 29, 2011. 3:02 PMBarnaby Walters says:
I have heard that 'lacquer applicator' pens work very well as their ink flows better and is a bit gloopier than the thin permanent marker pens. I was using a sharpie, and found that, whilst the thin end was required for the smaller details, I actually got fantastic results with larger traces using the felt end.

The rapidograph looks interesting — I may have to get hold of one of those.

P.S. My PCB soldered very well — on to testing now :|
Jul 14, 2009. 3:15 PMcold.geek says:
You've just rinsed copper chloride out of the sponge and down the sink, which means you've not eliminated the disposal problem but you've ignored it. The main issue in the disposal problem isn't because of the the large amount of Ferric chloride that doesn't react with the copper, but the small amount of it that does.
Nov 26, 2011. 3:49 AMAgent24 says:
Exactly!

Disposing the etchant in small amounts over a long time is no different than disposing the whole lot at once, it would all still end up down the drain.

Better to collect it all up (whatever way you etch) and take it to a proper disposal place in the end.
Jan 10, 2011. 9:05 AMdawning says:
Indeed and I'd worry that the Ferric Chloride solution isn't fully reacted.. Which, in draining through my pipes, of which some of my plumbing is copper.. well.. yeah... No thanks.

Where I live the local firehall will take whatever chemicals. You just drive them over in an onimous container and they'll add it to a big pile of mysterious things.
Feb 3, 2011. 5:31 AMnaughtyhorse says:
copper used in drainage?
good lord :-)
all mine's pvc
Dec 30, 2010. 4:24 PMJimmy Proton says:
A little bit on a sponge will quickly be diluted in the water and wont harm anything.
Jul 16, 2009. 8:04 AMworldgnat says:
So what is the best way to dispose of the resulting solution? I'm sure it varies from place to place, but is there a site where one can look these things up?
Mar 11, 2010. 7:22 PMtheblindferrengi says:
This is what the MSDS sheet says about disposal:

"Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. "

Its not much help, but I would take it to a landfill on one of their hazmat days, although its not illegal to dump it.
Jul 13, 2010. 6:39 AMhinge says:
you can mix the etchant(+ pieces of used sponge) with a baking soda solution-any concentration 3-5% will do.You end up with a mixture of undefined iron hydroxides and table salt solution.Should be less aggressive than FeCl3 and possible to flush down the drain.
Dec 16, 2010. 1:21 PMJTomM129 says:
Sounds like a good compromise . . .

That said don't forget you are using a tiny fraction of the FeCl3 solution that the "traditional" method calls for per. PCB (and I bet lots of that solution goes guess where?). Also, the small amount of solution that is used using this method gets diluted many times over will probably not effect house pipes to any measurable degree. Just flush with lots of rinse water after each session.
Mar 22, 2010. 1:45 AMrykonen says:
If Ford can continue to make cars, I think the earth won't mind a bit of used and diluted ferric chloride.  Am I the only one here who feels this way?
Sep 13, 2010. 11:09 AMAbsinthemadness says:
I would hope so.
May 31, 2010. 6:31 AMArex_x says:
No.
You should always be careful about what you put down the drain. But ...well , I don`t know really.
I see what you`re saying , about this being a small source of copper into the nature. And I think it is.
But it could have been interesting to do some math on it, sometime : )
Aug 18, 2010. 7:54 AMbeehard44 says:
....and down the drain it goes!

thats what i think when i pour stuff (harmful) down the drain
Nov 4, 2010. 6:44 PMhintss says:
just like the 5 microscope coverslips I broke in science a month ago. It ended up clogging the drain.
Dec 9, 2010. 7:39 AMtgrundle says:
I think some of you may be missing another important point here (even a year and a half later). This stuff attacks copper and the plastic the circuit board is made of. No mater if you have a newer or older home this stuff could attack your pipes. I don't think anyone wants to waste several days digging up and replacing pipe when we could be etching circuit boards!!! :)
Dec 20, 2010. 7:47 PMGitarGr8 says:
Copper drain pipes? Not very likely, even old sewer lines are typically made of clay, newer lines are usually ABS or perhaps PVC plastic. The reason people are / should be concerned with the proper disposal is because elevated levels of copper in a body of water is harmful to the fishies.
Dec 21, 2010. 9:38 AMGitarGr8 says:
That's like saying it's okay to dump your motor oil down the drain because the sewer treatment plant has an oil skimmer. What about people with septic tanks? People also tend to dump stuff in other places than the sink. What about storm drains? They lead straight to the ocean in my area. I just think it's irresponsible to tell people it's okay to dump materials that should be disposed of properly.
Dec 9, 2010. 9:07 AMworldgnat says:
Anyone have any thoughts on sodium hydroxide? Mixing it at three times the concentration of the ferric chloride should yield sodium chloride solution and ferric hydroxide precipitate, neither of which is that harmful (ok, so ferric chloride is an irritant, but it's not as dangerous as ferric chloride by a long shot.) The reaction will be violent, but done in sufficiently low concentrations (maybe <1M,) it shouldn't be too bad.

Am I missing something huge here, or is this a good idea?
Oct 11, 2011. 8:02 AMtechno guy says:
Say I do use sharpie to make the pcb, how do I clean it off to get to the untouched copper?
Nov 22, 2011. 4:12 PMak49er says:
A safer method is to use high proof (70-90%) isopropyl (rubbing) alchohol or denatured alcohol. Also works a treat as degreaser. Isopropyl can be picked up in the first aid section of most stores, denatured alcohol is sold as HEET (yellow bottle) gasoline treatment and at hardware stores.
Nov 13, 2011. 8:09 AMmjenkins1 says:
Great instructable Jim!

Those of you having trouble, I can explain. Jim is using 1/2 oz copper laminate. If you're using 1 oz, it takes considerably longer. I like using the 1/2 oz copper boards just for this reason - it goes so much quicker. (I've done it with both types of board.)
Nov 9, 2011. 10:23 AMabtrooper82 says:
Good idea, but didn't well for me. So unless I'm using weak ferric chloride I will stick to the etching tank method.

Thanks
Nov 9, 2011. 3:24 PMabtrooper82 says:
Hi

Good Question !

Not sure on the weight of the PCB, suspect around 1oz. The sponge was dry. The ferric chloride was a new bottle from the same supplier which I used in the etching tank set up. The PCB was create using the Laser printer transfer method, the board was fully cleaned before transferring the layout design.

So unless I'm doing something completely wrong (possible), it just isn't working. I would love to use this method, looks really good so anything else you can suggest would be appreciated.

Nov 10, 2011. 11:13 AMabtrooper82 says:
No just 1oz PCB I'm afraid. Sounds like the copper thickness, but will see if I can locate some 1/2 oz PCB
Nov 7, 2011. 2:41 AMksarodia says:
can i use vinegar in place of muriatic acid?
Sep 7, 2011. 2:42 PMdustinandrews says:
Thanks for this! It was very helpful.

I was having tons of trouble with the dextrin paper. If I failed to get a good transfer the first time, the copper was super hard to clean good enough. After some experimenting I found a process that works most of the time.

Clean the PCB with acetone.
Clean the pcb with a soft sponge and class cooktop cleaner.
Rinse well and clean with white vinegar.
Rinse well and clean with dish soap.

Then I replaced the dextrin paper with "Reynolds Brand Genuine Parchment Paper" (kitchen supply stuff)! I used double sticky tape to put it on top of regular paper for the trip through my laserjet. (YMMV with double stick tape in the guts of a printer! You can easily cut it into big enough sheets not to need that if you worry.)

Toner sticks well enough to the parchment paper, but just barely. One pass through the laminator and the traces were fused perfectly and no need for the soaking. Due to the transparency of the parchment paper lining up double sided boards is easy in any light. The biggest problem is that the board doesn't stick to the paper even a little so you need to be careful when feeding it into the laminator that it does not shift. An iron would probably not work if the paper shifted under it at all.

Aug 28, 2011. 5:31 PMtriodo says:
alguien sabe si este producto de radioshark lo venden en ecuador sur america ?
Jul 30, 2011. 12:48 AMtlynch1 says:
any reason you couldn't use dychem for the mark?? i think it comes in a pen also.. used in machine shops everywhere
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I'm the Founder and Chairman of TechShop.