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Sponge + Ferric Chloride Method -- Etch PCBs in One Minute!

Step 4Clean Up (Not Much To Do)

Clean Up (Not Much To Do)
The clean up really is just a matter of rinsing out the sponge, throwing away the rubber gloves (or rinsing them off for reuse), and cleaning any spilled drops of ferric chloride from the work surface.

You can reuse the sponge over and over, so rinse it and let it dry, and keep it with your bottle of ferric chloride.
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13 comments
Mar 21, 2012. 6:26 PMwilliamhaze says:
Are there any hazardous fumes produced during this process? I was thinking of doing this for a presentation in class without windows. Thanks!
Jul 14, 2009. 3:15 PMcold.geek says:
You've just rinsed copper chloride out of the sponge and down the sink, which means you've not eliminated the disposal problem but you've ignored it. The main issue in the disposal problem isn't because of the the large amount of Ferric chloride that doesn't react with the copper, but the small amount of it that does.
Nov 26, 2011. 3:49 AMAgent24 says:
Exactly!

Disposing the etchant in small amounts over a long time is no different than disposing the whole lot at once, it would all still end up down the drain.

Better to collect it all up (whatever way you etch) and take it to a proper disposal place in the end.
Jan 10, 2011. 9:05 AMdawning says:
Indeed and I'd worry that the Ferric Chloride solution isn't fully reacted.. Which, in draining through my pipes, of which some of my plumbing is copper.. well.. yeah... No thanks.

Where I live the local firehall will take whatever chemicals. You just drive them over in an onimous container and they'll add it to a big pile of mysterious things.
Feb 3, 2011. 5:31 AMnaughtyhorse says:
copper used in drainage?
good lord :-)
all mine's pvc
Dec 30, 2010. 4:24 PMJimmy Proton says:
A little bit on a sponge will quickly be diluted in the water and wont harm anything.
Jul 16, 2009. 8:04 AMworldgnat says:
So what is the best way to dispose of the resulting solution? I'm sure it varies from place to place, but is there a site where one can look these things up?
Mar 11, 2010. 7:22 PMtheblindferrengi says:
This is what the MSDS sheet says about disposal:

"Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. "

Its not much help, but I would take it to a landfill on one of their hazmat days, although its not illegal to dump it.
Jul 13, 2010. 6:39 AMhinge says:
you can mix the etchant(+ pieces of used sponge) with a baking soda solution-any concentration 3-5% will do.You end up with a mixture of undefined iron hydroxides and table salt solution.Should be less aggressive than FeCl3 and possible to flush down the drain.
Dec 16, 2010. 1:21 PMJTomM129 says:
Sounds like a good compromise . . .

That said don't forget you are using a tiny fraction of the FeCl3 solution that the "traditional" method calls for per. PCB (and I bet lots of that solution goes guess where?). Also, the small amount of solution that is used using this method gets diluted many times over will probably not effect house pipes to any measurable degree. Just flush with lots of rinse water after each session.
Mar 22, 2010. 1:45 AMrykonen says:
If Ford can continue to make cars, I think the earth won't mind a bit of used and diluted ferric chloride.  Am I the only one here who feels this way?
Sep 13, 2010. 11:09 AMAbsinthemadness says:
I would hope so.
May 31, 2010. 6:31 AMArex_x says:
No.
You should always be careful about what you put down the drain. But ...well , I don`t know really.
I see what you`re saying , about this being a small source of copper into the nature. And I think it is.
But it could have been interesting to do some math on it, sometime : )
Aug 18, 2010. 7:54 AMbeehard44 says:
....and down the drain it goes!

thats what i think when i pour stuff (harmful) down the drain
Nov 4, 2010. 6:44 PMhintss says:
just like the 5 microscope coverslips I broke in science a month ago. It ended up clogging the drain.
Dec 9, 2010. 7:39 AMtgrundle says:
I think some of you may be missing another important point here (even a year and a half later). This stuff attacks copper and the plastic the circuit board is made of. No mater if you have a newer or older home this stuff could attack your pipes. I don't think anyone wants to waste several days digging up and replacing pipe when we could be etching circuit boards!!! :)
Dec 20, 2010. 7:47 PMGitarGr8 says:
Copper drain pipes? Not very likely, even old sewer lines are typically made of clay, newer lines are usually ABS or perhaps PVC plastic. The reason people are / should be concerned with the proper disposal is because elevated levels of copper in a body of water is harmful to the fishies.
Dec 21, 2010. 9:38 AMGitarGr8 says:
That's like saying it's okay to dump your motor oil down the drain because the sewer treatment plant has an oil skimmer. What about people with septic tanks? People also tend to dump stuff in other places than the sink. What about storm drains? They lead straight to the ocean in my area. I just think it's irresponsible to tell people it's okay to dump materials that should be disposed of properly.
Dec 9, 2010. 9:07 AMworldgnat says:
Anyone have any thoughts on sodium hydroxide? Mixing it at three times the concentration of the ferric chloride should yield sodium chloride solution and ferric hydroxide precipitate, neither of which is that harmful (ok, so ferric chloride is an irritant, but it's not as dangerous as ferric chloride by a long shot.) The reaction will be violent, but done in sufficiently low concentrations (maybe <1M,) it shouldn't be too bad.

Am I missing something huge here, or is this a good idea?
Jul 16, 2009. 7:17 PMRusdy says:
WOW!!! Thanks for sharing this! THis is definitely the simplest way to etch my board from now on!!
Jan 5, 2010. 4:31 PMerod998 says:
i know this is awesome!!!!
Jul 16, 2009. 1:28 PMhairybaroque says:
We are worrying about polluting the water system with tiny quantities of a known fungicide. Would it work to paint your decking or garden fence with the leftovers on a gradual replacement basis? The different colours from the iron and copper in the solution might look nice …
Jul 16, 2009. 11:53 AMmortso says:
Call your local Waste Management company. They'll be able to steer you to disposal sites for toxic chemicals.

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