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There isn't much here in the way of instructing as the mounting of a pegboard and framing are easy enough and no-doubt have been covered in other great instructables. On the other hand my OCD and it's need to organize and have everything in its proper place led to this creation, my Wii Game Rack. Epic win I say, epic win.
I, too, am very OCD about organization of all collections. I don't think you did this, as I don't see any lines peeking through in your pic, but my first thought was the old standard a lot of ppl use on pegboard organization boards for tools in the workshop - outlining each stored piece so there is no doubt where it "lives" on the board. I've even seen the addition of written or adhesive labels inside said outlines for extra "protection" (? lol) against disorganization...by others, not the storage creators, of course! ;)
Idea: This would work well hung on inside of closet door(s) - so out of sight/way when not needed - or even could do (on smaller scale) on entertainment cabinet doors (inside), if it were an issue to see it all the time or if wall space is in short-supply. Now, if I could just devise the perfect DVD storage system - neat, easy, good-looking and ever-expandable...I've been stumped for years with that one - while my collection continues to grow steadily...argh