Distilling Basics

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Introduction: Distilling Basics

About: I like to make things

this is a companion to my instructable, how to make moonshine, that will explain the basics of distillation. with all of the questions i have received, i find it necessary to write a small primer about what the distillation process is all about. this is not a scientific treatise or journal article. i am not a scientist. i will not get too far into chemistry. this is just the basics, folks, so take that to heart before you berate me for my gross oversimplification of this topic.

distilling is simply a way to separate different liquids dissolved in a solution. henceforth i will refer to each individual component of the mixture as a 'liquid,' and the mixture as a whole as the 'solution.' using a simple pot still such as the one in my fore mentioned instructable i will show the basic science involved in distillation.

i hope this clears up a lot of the questions out there. read up and enjoy.

Step 1: Apparatus

refer to my instructable how to make moonshine for the basic physical set up. this is what is known as a pot still and is the easiest type of still to build and use. reflux and column are alternate still types that can be used with higher levels of efficiency, but with the trade-off of more difficult construction and operation. in principle, though, they all work the same way. i, however, will focus solely on the pot still.

Step 2: Science

when i was in seventh grade science class we had a project toward the end of the year that was the culmination of what we had learned throughout this class. it was a big part of our grade and was consequently of great importance. it was called 'mystery lab.'

we were each given a jar containing a random assortment of anything our teacher felt like including--solids, liquids, even dissolved solids. we were then responsible for identifying everything in the solution based on the scientific techniques we had been taught up until this point.

the larger objects--like paperclips and nuts and bolts, etc.--were easy to filter out and identify. where this little story becomes poignant is in the clear liquid left over. this was not simply water, and we had to figure out what was in it. for this we used distillation. distilling this solution while graphing boiling points allowed us to cross reference our graphs with known boiling points and therefore identify each individual liquid in the solution, thus earning a high mark. with this knowledge, you can use a homemade still to make strong alcoholic beverages. who knew they were teaching us how to make moonshine in middle-school!

Step 3: Graphing? Excuse Me? I'm Just Trying to Make Booze

the short answer is no, you don't have to graph. in mystery lab we started with something the contents of which we had no idea. in distilling for liquor we pretty much know what is in there and what to look for. it will help, however, to understand the graphing process in order to understand distilling in general. therefore i will explain it.

whether you use a pot still, or simply a test tube over a Bunsen burner (which is pretty much just a small pot still) the principle is the same. as you run your solution through the still, every 30 seconds to 1 minute record the temperature of the solution in the the pot. when the temperature remains the same for any length of time it will produce what is know as a 'plateau' on your final graph (if you were to actually graph it out). each temperature plateau will correspond to the boiling point of a specific liquid in your solution and can therefore be identified and either retained or discarded.

each type of alcohol (methanol, ethanol, etc.) boils off at a different temperature. and this is the basis for distillation.  by using a little bit of scientific knowledge and a pen and paper, you can find out exactly what is coming out of your still.  this is very important and should not be overlooked. 

in order to have a reference for what you are getting at any given temperature, check out this boiling point calculator. it is not mine and i cannot guarantee it's veracity, but it looks good, from what i can tell.  you can also google the boiling points of methanol, ethanol and water.

Step 4: The Big Difference

when you don't know what you have and want to find out you will basically run the still until almost dry and then look back at your graph of boiling points to determine what is actually in the solution. with distilling for drinkable liquor you are only concerned with a very specific boiling point:: that of ethyl alcohol, or ethanol. this is where the terms 'heads' and 'tails' comes into play. the heads are anything that boils below the boiling temperature of ethanol and the tails are anything that boils above it.

as the temperature of your pot rises, you will collect and consequently discard anything that corresponds with a boiling temperature less than that of ethanol and in turn do the same for anything boiling at a higher temperature. anything that is boiling off at a temperature corresponding to ethanol's boiling point at your particular elevation, etc., is what you are seeking. once your temperature has increased to a level greater than the boiling temperature of ethanol you can turn off the heat and stop the run. there is no reason to burn it dry in this case.

for instance, if your solution contains methanol, ethanol and water it will happen like this: once the temperature of your solution reaches around 148 °F methanol will begin to boil and come out through your tube as vapor into your condenser where it will convert back to liquid and exit into your receptacle.  the temperature of your solution will not vary much beyond 148 °F until the methanol is gone and then will begin to climb again until it reaches 173 °F, the boiling point of the ethanol.  the same thing will happen here.  the temperature will hover around the same until the ethanol is boiled off and then on to water. 

in order to get ethanol and exclude the rest you get rid of what are called the 'heads' and 'tails.' basically dump anything that boils lower than around 173 °F and everything after the temperature begins to climb again.  more than one receptacle could help in this case. use one for the heads, one for what you want, and one for the tails.

after a run through your still, tossing out the heads and tails, you should have left a bit of alcohol and water worth drinking. multiple runs will distill to an even greater proof, up to a point.

welcome to the wonderful world of distillation, folks.

let me know if any of this doesn't make sense and i will correct it in the instructable. thanks for reading and i hope this helps.

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    Hello can I just use cherry juice to make a mash instead of real cherries,with water,yeast and sugar?

    83 Comments

    Great article. Now I understand the complete process on heads and tails. Thank you!

    Using the pot still method, what would be the average ethanol yield per pot?

    This is very interesting and i have detained much from this eloquently drawn passage.

    1 reply

    Thank you so much for your kind words!

    Is there a way to test to make sure you have all of the methanol out of the ethanol solution, other than just plotting temperatures?

    2 replies

    Distill again and akeep a close eye on change in temperature.

    Does a Sugar/water/yeast wash usually contain methanol??

    1 reply

    More often than naught

    This Instructable completely cleared this up for me. THANK YOU!

    You say around five lbs of sugar to three gal of water how much yeast to that ?

    so where im from maple syrup season is just round the corner. maple syrup is made of a cooked down tree sap. tree sap is as a whole sugar and water. now ive never made liquor but im thinkin my first try may be with this simple sugar mixture. any thoughts?

    with the wash, do you put the water suger in the kettle and threw the pipe like you do to get ethonal and methonal out of the water?

    1 reply

    also do i leave the ethonal in the brew?

    funny.marry christmas.. 2009 it was you said. it is now x mas eve 2012. this is the best explanation after many day of research. thanks can not post to proper post

    hey all,
    i didnt get any run off or significant break at 148F, did i not wait long enough? any help is appreciated.
    jjay01

    This is really interesting a story-tell and a step-by -step guide combined! I've been reading your posts and I'm really learning a lot! I made my first run using a copper pot distiller which I bought just lately. I tried and use your moonshine recipe and it awesomely worked! Well just to add, for those who have the same pot still as mine or at least interested in home distilling, this page might also help you: http://www.whiskeystill.net/pages/how-to-distill . I found this thing while I was eyeing on starting this hobby :)

    Hello everyone im new to this stuff and wonder if any of u has any good tips

    Can I use a aluminum pressure cooker for my pot? Some people mention it in their instruction and other dont. I had built one before reading other saying no. Do I start over??

    at 25gallons of water how much sugar and yeast should a man at to the wash this is a hell of a good page i completely understand it all. been around it all my life but you put it in the langauge that i speak and understand thanks