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more info on penny history: http://ky.essortment.com/historypenny_rmor.htm
or from: http://www.usmint.gov/about_the_mint/fun_facts/index.cfm?flash=yes&action=fun_facts2
Following is a brief chronology of the metal composition of the cent coin (penny):
The composition was pure copper from 1793 to 1837.
From 1837 to 1857, the cent was made of bronze (95 percent copper, and five percent tin and zinc).
From 1857, the cent was 88 percent copper and 12 percent nickel, giving the coin a whitish appearance.
The cent was again bronze (95 percent copper, and five percent tin and zinc) from 1864 to 1962.
(Note: In 1943, the coin's composition was changed to zinc-coated steel. This change was only for the year 1943 and was due to the critical use of copper for the war effort. However, a limited number of copper pennies were minted that year. You can read more about the rare, collectible 1943 copper penny in "What's So Special about the 1943 Copper Penny.")
In 1962, the cent's tin content, which was quite small, was removed. That made the metal composition of the cent 95 percent copper and 5 percent zinc.
The alloy remained 95 percent copper and 5 percent zinc until 1982, when the composition was changed to 97.5 percent zinc and 2.5 percent copper (copper-plated zinc). Cents of both compositions appeared in that year.


































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The policy has an exemption for treatment for artistic, educational and like purposes but only when the coins aren't being used for their metal value. And the use of the coins as washers might count as use for metal value.
Is it illegal to damage or deface coins?
Section 331 of Title 18 of the United States code provides criminal penalties for anyone who “fraudulently alters, defaces, mutilates impairs, diminishes, falsifies, scales, or lightens any of the coins coined at the Mints of the United States.” This statute means that you may be violating the law if you change the appearance of the coin and fraudulently represent it to be other than the altered coin that it is. As a matter of policy, the Mint does not promote coloring, plating or altering U.S. coinage: however, there are no sanctions against such activity absent fraudulent intent.
Modifying or mutilating any US currency is only illegal if it is aimed at mis-representing the value.