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simple Copper plating

simple Copper plating
CAUTION: this instructable involves the dismantlement of old batteries which will expose you to hazardous substances. 
I f you must do this.. follow utmost caution, and wear protective eye gear


A simple rig for electroplating small objects.. like keys, jewelry etc..
Using easily available objects.. except for one chemical which should be available at a chemist/drugstore/hardware shop.

Brief history of when i did this-

Why don't they teach this stuff in school?

My best memory from school was when i was in class 7 or 8 in a school in Shillong(north east India). There was a chemistry assignment that had to be done. The teacher told us to do one of the handful of exercises that were in the textbook. Most of it was ridiculously inane stuff like the "graphite conducts electricity" one.. or the "make your own electric bell" one. Me and a friend decided to do something a bit more challenging..

so we picked the last one - "copper plating".

This was more of a paragraph in the chapter text than an actual exercise.. it just had a bare description of the copper plating process and the chemical reactions involved.

No wonder our teacher was skeptical about it and told us that we would probably flunk if we didn't do one of the more "reliable" exercises(the graphite one and the stupid electric bell)

Anyway dday arrived and after a really long hour during which each kid showed off their ridiculously identical and lame graphite conduction and electric bell projects it was our turn.

unfortunately we had only managed to secure one of the key ingredients(copper sulphate) that very day.. so we hadn't even tested the rig yet! but we didn't tell the teacher that. we confidently set up the rig on the floor next to her desk(i guess she was a bit concerned about the "toxicity" of the shimmering blue compound.

 i dumped a key that i wanted plated, and a volunteer from the audience(we sort of felt like magicians doing a show) gave us some small metal thing(think it was a earring or something) and we flipped the switch.

in a few minutes the metal objects turned a flakey orange-yellow... APPLAUSE!

Why don't they teach this stuff in school?

 
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Step 1You need:

you need:
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  • carbon-rod.jpg
  • copper-elec.jpg
1) atleast 3volts(2 AA batteries) for it to work well. will work with 1.5v(1 AA battery) too, but will be really slow. Will probably work really well with more power.

2) a carbon electrode. we got ours from an old battery. its the inner black colored core.

3) a copper electrode. we hammered a bit of copper wire till it was flat. a bit of copper tube might work too.

4) wires

5) a jar/beaker

6) water

7) copper sulphate. we ended up getting some from the chemistry lab.
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20 comments
Feb 16, 2011. 4:21 PMDumchicken says:
does vinegar work?
Mar 3, 2011. 3:32 PMDumchicken says:
also well i want to say to every one ho read this


DO NOT ATEMPT TO OPEN A BATTERY YOU WILL SQUERT ASID IN YOUR
EYE

sorry but this is not safe

p.s. use penneys insted they work just as well(with vinegar)
Apr 11, 2012. 8:10 AMgeorion says:
squirting?? otherwise YEP .!!!
Mar 19, 2011. 6:27 PMDumchicken says:
well if your yousing a hammer to open it...
Jul 13, 2010. 10:19 AMyouper0 says:
..How does this work with the key just siting in the liquid????
Apr 11, 2012. 8:08 AMgeorion says:
yes-thats the way its done
May 25, 2011. 2:59 PMNirgal38 says:
The sort of battery from which you'd get a carbon rod is the old style dry cell, not one of the newer alkaline batteries. The black powder surrounding the rod is manganese dioxide, a useful chemical but it should be handled with caution. It's also messy as all get out so do it outside.

These batteries (actually, they are cells... Batteries are made of several cells in a series) shouldn't contain any liquids to "squirt" into your eyes. Nevertheless, anyone working with chemicals without proper eye protection is asking for trouble.
Jul 13, 2010. 6:15 PMsilencekilla says:
you spelt "earring" wrong. you spelt it with only one "R". Lol sorry i had to point that out.
Apr 24, 2011. 1:35 PMimajem says:
And you spelled spelled wrong!!! Nitpicker....
Jul 13, 2010. 8:02 AMPKM says:
I think you'd have better success if you attached the key to the negative electrode- this Wikipedia article explains why. You can actually do without the carbon electrode completely if you just attach the negative electrode wire straight to the key or metal object.  I suspect that your experiment was doing a simple substitution reaction: iron in the key reacts with copper sulphate in solution to give iron sulphate and copper metal. 

Still, kudos for going above the basic level your school expected and actually finding something out for yourselves.  I did a similar thing in my first year- we were meant to measure the amount of carbon dioxide given off by yeast by counting the bubbles, but my friend and I figured this would be more accurate and less boring if we captured the gas in an inverted measuring cylinder and found the actual volume.  

The science teachers listed possible flaws with the experiment, and we gave solutions to them until they just let us do it our way to shut us up :)
Dec 19, 2010. 5:46 AMArano says:
your suspection is totaly right... it is all about the standard potential of the elements/ions used ( http://en.wikipedia.org/wiki/Standard_electrode_potential_%28data_page%29 ) the reaction works without electrodes and there is one similar reaction you really should try out. with this you reaction you can make 'gold' (well it's brass but looks similar) just throw a piece of zinc into the copper sulfate solution. (learned that at school when i was 14 i think)
Jul 16, 2010. 3:04 PMHeWantsRevenge says:
yea...i think u goto hang whatever u wanted plated to the negative so the copper is attracted the object. at the very least...hang the said object for a good even coat

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Author:chaitanyak(chaitanyak.com)
a Designer and Digital illustrator, working full time as a web and game designer. Work mostly on fun online media like Web games and rich web content. In my free time(when i'm not gaming) i do a lot o...
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