the idea came from an older copy of wikipedia's "Photoelectric effect" article (most images from wikipedia pages).
at this point its just an idea, so dont be critical as i havnt built it. but for those considering building, it should be constructable from household bits.
Step 1: Photoelectric Effect
The photoelectric effect occurs when short wavelength electromagnetic radiation (commonly known as visible light and UV light) strikes a surface causing elecrons to be emitted, making the surface positively charged.
according to the patent (i mean wikipedia reference), the surface struck is covered with an insulator (i would suggest black electrical tape) and is shiny or polished. it shouldnt be a perfect insulator, maybe megaohmic.
the metal beneath the insulator replenishes the lost electrons in the insulator and grows positively charged.
Step 2: Capacitors
as seen on the intro page, it has a capacitor, i would suggest the simple Leyden Jar as a good one, though i highly reccommend caution as these can store high voltages and i reccomend research before using one. if enough used it can be lethal. My tip would be to have a significant load on so it cant go so high or clearly mark High voltage and exercise caution.
they can be constructed by a layer of alum foil lining the inside and outside. a self charging one could be made with salt water on the inside (charged by shaking).
if you want to use electrolytics then remember the solar panel side is positive charged, the electrons are attracted from the earth connection to fill the negative side, i dont know if that would allow low volts/high current.
Step 3: Load
supporting the plate on top of the jar could be ideal, as shown, or you can be adventurous and design more compact designs. like another insulator under the top plate (no light to go on that one) with another plate under that for the capacitor. possible water cooling but that could hinder electron emission as the old valves needed a heater to emit the electrons.
i hope you enjoyed it, as i said its an idea, perhaps the cheapest solar panel with the most output that you can get.