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Yes you could, please look here how to PROPERLY wire a solar panel and add a recharge module on your NiMHhttp://www.produktinfo.conrad.com/datenblaetter/550000-574999/553893-an-01-en-CONRAD_LERNPAKET_AKKUS___LADETECHNIKEN.pdf
Yes, you should manage your current flowing. Otherwise, if it is dark, the battery will drain through the solar panel! Please read this document to understand how to properly charge your Lithium battery with a solar panel/http://www.produktinfo.conrad.com/datenblaetter/550000-574999/553893-an-01-en-CONRAD_LERNPAKET_AKKUS___LADETECHNIKEN.pdf
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