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I think we had the same problem as you with the mushroom cap silicone curing very slowly compared to the stems when covered in cling film. We had tended to add more paint to the stems meaning they were darker and think this had an effect on drying, it might also have been the shape in which the cling film was made, a tube with open ends, that meant they dried quickly, but for the caps we tried to added them to a solution of water and baking powder and it did seem to speed up curing time, though we didn't do it scientifically so couldn't say for certain. I was using the Acetoxy Silicone, next time I'll try to find the recommended stuff.
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