i dont really have any ideas but i do know that u can use suger as pumice would be used in soap. im not shure how this would work out.
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What about castille soap? It's made from vegetables.
You could use lemon juice. The acid in it kills a lot of bacteria, and it is indeed environmentally friendly. The only problem is that lemon juice acts like water, and is not a gel-like substance like ordinary liquid soap.
If you do that, make sure that you either get the juice from the lemons yourself, or make sure that whatever lemon juice you buy is made from real lemons.
Lemon juice is anti-microbial, but it requires at least ten minutes of soaking to work effectively. Also, lemon juice does not dissolve oil, so you would still need some kind of detergent to remove the bacteria in your skin oil.