Particularly the motorized window blinds controller.
. It depends on how many amps the wire has to carry. 20 AWG is good for 3-5 A (depending on how it is used). 14 AWG will safely handle 15 A (more in free air).
. Voltage determines the type/thickness of insulation needed.
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depends on the voltage, but almost anything will work(unles ofcourse you try to pump 110v into a tiny wire),