This is an old request but, here's my 2 cents: I personally like embroidering rag doll eyes with the French knot stitch. For a baby or young child avoid adding beads to it or buttons that could be a choking hazard is detached.http://www.embroiderersguild.com/stitch/stitches/french.htmland the web is rich with videos showing you this technique.
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Are you embroidering eyes on a doll for a baby or do you want to duplicate the look made with cosmetics known as "baby doll eyes" in embroidery? Hand or machine embroidered?