use masking tape its very good. I made two batman mask and one ironman mask also i made one batman mask out of duct tape and parts of flash lights.i also made one out of electrical tape and it came out good.
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making a form-fitting mask requires a lot of work. You need to cast your head (usually in stone or fiberglass) and then sculpt the shape of the mask on that cast. From there you would cast it out of urethane (most likely) . There are alternatives. I would recommend you look at the "Duct Tape Batman Mask" as it's a simpler version of what I've described.
yeah heres the link to that instructable www.instructables.com/id/Duct-Tape-Batman-Mask/