Why not just ask?
If you are hacking a "Friend's" just ask them.
There are many ways, but I won't discuss them here
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hello.....i m a student and i want hacking tool email i.d hacking tool but i m seeing all the sites in goolge and others one but i cant find so u have a hacking tool plz send me this but i cant give u money for this but i have a great software to pay u in this regard so plz give if u can ur friend Abdur Rehman Naeem 13/06/2010
why would you do this to a friend?
1. set up Firefox on your computer.
2. Set it so it always remembers password.
3. have your friend check their email on it.
4. check what the password is.
The same way you do it to someone you don't like.