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The hot stuff in pepper juice is an acid. After working with chilies generously moistenyour hands with lemon juice then add a bit of bicarbonate of soda to make a paste. Scrub your hands vigorously with this paste paying particular attention to the cuticle and under the nails. Rinse well with warm water. If in doubt repeat. If you did in fact touch your eye, mix 1/2 teaspoon of bicerb. in a glass of warm water. Pour into the eye while blinking rapidly in order to scrub the eye. Rinse with cool water. The bicarb. and water mixture works well for washing your Willie also. I know, I speak from experience.
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