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Pyrolizing is the burning in the absence of Oxygen. The Argon doesn't make is special, but it DOES replace the oxygen in the chamber. The oxygen would be burned off pretty quickly in a sealed chamber, but in a toaster, the resupply would lead to a lot of CO2 (where the oxygen mixes with the Carbon in the burn down process) which is very different in behavior than CO2. So this LOOKS like burned bread, and it IS, but in the absence of Oxygen - so it is C, not CO2. "Brown's Gas" is the flammable byproduct that is giving the yellow flames mentioned. I hope that helps.
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