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Produce a Rich Rust Patina on Iron and Steel, Safely and Quickly, Using Common Household Chemicals

Produce a Rich Rust Patina on Iron and Steel, Safely and Quickly, Using Common Household Chemicals
  This instructable will show you a fast, safe method, using common household chemicals that you probably already have, to produce a rich rust patina on iron and steel to give it a weathered, aged appearance.

Background

I've had this Maine 'buoy bell' wind chime for about eight years now. I really like it. It has the haunting melancholy sound of a bell buoy at sea being tossed by wind and waves. It is made of COR-TEN steel which is designed to rust on the surface to create a protective barrier against further rusting. It came painted black on the outside and was supposed to develop this rich rust patina naturally over time. Well, the unpainted inside did rust completely after about a year, but the outside only rusted slightly, near the bottom, even after exposure to the sun, rain, and snow of the northeast for eight years. I wanted it to have a nice rust patina that looked like it had been hanging on the eaves of a lobster shack, at the end of a pier, for many a year, being splashed and buffeted by nor'easters and sudden gales. Seeing it was taking so long, I decided to take things into my own hands and, ah, "help" mother nature along and accelerate the process. I searched the net and found mostly dangerous methods to induce rust on steel using highly caustic or acidic chemical solutions. However I finally did find a simple safe method, using on-hand household chemicals, buried deep within a thread on the subject at a metalworking forum. I got spectacular results which have not only withstood the wind and rain of the southwest but have actually improved with the help of mother nature. I like the results so much, and there is so little practical information on the subject that is accessible to the general public, I thought I'd share this simple method with the instructables community.

Judging by the number of posts on forums asking how to do this, I see I am not the only one who wants to actually promote, rather than prevent, rust on iron and steel objects. I found out the basic information for doing this at the very cool ArtMetal forum: http://www.artmetal.com/blog/bob_turan/2009/04/rust_promoter . I'm guessing that there are more than a few instructables members who have a similar desire to prematurely age some iron/steel artifact, so I encourage people to post pictures of their resuls in the comments and add tips on how they did it so we can all learn. This method is not set in stone. Posts about useful variations on the method are always welcome.
 
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Step 1Materials and Tools

Materials and Tools

You will need the following:

Household Chemicals:

  • White vinegar (any brand)
  • Hydrogen Peroxide (3% -- use a fresh bottle)
  • Table salt (any kind will do, doesn't have to be sea salt)
  • Degreaser (any brand)

Tools:

  • Measuring cup
  • Measuring spoons
  • Spray bottle
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31 comments
Aug 4, 2011. 2:34 AMdoomsdayltd says:
d@mn i shouldn't of bought my rust type paint, this does the exact same effect for 6 dollars when i spent like 16 for the real rust paint :(
Aug 4, 2011. 8:16 PMdoomsdayltd says:
well what the rust paint does is it puts a layer of paint with iron oxide in it, then the other solution you put on promotes rusting of the iron oxide. and yes this method is only like 6 dollars since how inexpensive the items were for this.
Sep 16, 2011. 7:41 AMgypsyloot says:
Hi Laral- your details were really helpful to me, so glad I came across this. I didn't notice if you posted your "cheap way" to produce the green patina ... if you're able to I would very much appreciate it!! ... thanks ;-)
Nov 9, 2011. 7:03 AMJGsoldier says:
can this work on coins or other metals?
Aug 19, 2011. 3:48 PMmrlunna13 says:
I have always hated the rusted look, and have been almost obsesive about removing even the smallest hints of rust. But I have to admit, it looks kinda cool.
Cheers,
Mr. Lunna XIII
Jul 30, 2011. 1:14 PMshealyum says:
You wanna see a rust world visit www.rustpainting.com there you will see a variety of rust paintings from all over the world. There is a good interview on rust painting with an Irish artist Sean Healy.
Feb 22, 2011. 10:45 AMsoapmaker72 says:
I have used this proceedure on my latest work. Please visit www.jtbmetaldesigns.com for more information.
Oct 27, 2010. 7:28 PMZeppelinfreak says:
Did you strip the paint off of the bell or did you apply the solution right to the painted steel?
Jul 10, 2010. 10:17 PMYoungPyro19 says:
This instructable has been very helpful to me since I'm trying to produce Fe2O3. 5 stars...
Jul 12, 2010. 6:43 PMYoungPyro19 says:
Yes, I know but this naughty boy has plenty of steel wool and little money to pay for shipping.
Jul 14, 2010. 8:52 PMYoungPyro19 says:
I appreciate your concern but this 19yr old kid is out of high school and has never taken a chemistry class in his entire life. Although, I have taken biology but that was out of a text book. I have more research to do before I get started on thermite but producing Fe2O3 is just another stepping stone. Did you see my instructable on making German Dark Al powder from foil? I might mix my homemade Al with my homemade Fe2O3 for thermite. I’ll let you know how it goes. Here is a picture of my final product. One sheet of steel wool got me 14g of Iron(III) Oxide. It took approximately 4 days for the steel to transform.
Jul 15, 2010. 5:10 PMYoungPyro19 says:
Thank you… You know I never thought to ground myself until I watched something on T.V. about the science of fireworks and Zambelli Fireworks. Before the pyrotechnists enter one of their buildings to construct fireworks they ground themselves on a copper plate. I have some copper wire so I think I’ll start doing that. I want to practice safer procedures as I carry out more of my experiments. Back in ’05, ’06, and ’07 I was very ignorant about safety and pyrotechnics. Over these couple of years I have learned plenty. Actually, believe it or not, the steel wool rusted into somewhat of a coarse powder. There was no ball milling needed. I did however; grind the iron(III) oxide a little in a plastic container with a paint stick. The process was easier and cheaper than you think thanks to your and acecase’s instructables.
Jul 19, 2010. 1:33 PMYoungPyro19 says:
Wait a minute, I misspoke here. I'm not going to ground myself; I'm going to discharge any static build up I may have onto a plate that is grounded before I get to work with my explosive compounds and chemicals. That’s what the pyrotechnists were doing, sorry. Grounding myself and the materials I'm working with would be going overboard. As far as I know the Chinese don't do that while making fireworks and they don't have a lot of accidents.
Jul 18, 2009. 11:09 AMvalhallas_end says:
I love these bells - a few of them together makes a really eerie melody. We cleaned and painted one with a sea scene for fun, but I like the rust (ours refused to rust, so we think it was 'proofed). Yours looks like a good match for a beach house or old trawler.
Jul 21, 2009. 5:14 PMvalhallas_end says:
You know, I never thought of recording them ringing...I wish we still had all of ours. After we painted the seascape, we did the rest for relatives, so we only have the one left...although a salvage shop I like on Cape Cod always has a few, so I might pick up some this year. Maybe I'll make a tuned wind chime with them....hmmm...
Jul 22, 2009. 12:58 PMvalhallas_end says:
Yup - every three or four months, they buy derelicts' salvage from the divers, or buy pieces tourists managed to grab on the licensed dive spots all along the coast. They also buy from shipyards and outfitters. Granted, they also resell stock from other stores mixed with real salvage (gotta make a living somehow!), but the buoy bells are authentic and all of their brasswork is real. It's pretty cool to sort through. There's another, more hardcore salvage shop further up the Cape, but his prices are far higher.

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Author:Laral