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I'm an artist who using just about anything in my art projects, a type of recycling.
I haven't posted in a while because my digital camera died and I'm looking for a replacement.
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The reason for boiling outside is to let the caustic fumes from the peppers to disperse. I did it inside once and my eyes burned pretty bad. It's not to sterilize the peppers but to extract all the flavor from them.
The sugar may hamper the extraction of the flavor from the peppers and keeping it boiling for some time may end up burning the sugar.